860278-87-1

Basic information

• Product Name: 2,2,2-trichloro-4-fluoro-1,3,2λ⁵-benzodioxaphosphole
• Synonyms: 2,2,2-trichloro-4-fluoro-1,3,2λ⁵-benzodioxaphosphole
• CAS NO: 860278-87-1
• Molecular Weight: 263.42
• Mol File: 860278-87-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2,2-trichloro-4-fluoro-1,3,2λ⁵-benzodioxaphosphole(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,2-trichloro-4-fluoro-1,3,2λ⁵-benzodioxaphosphole(860278-87-1)
• EPA Substance Registry System: 2,2,2-trichloro-4-fluoro-1,3,2λ⁵-benzodioxaphosphole(860278-87-1)

Safety Data

• Hazardous Substances Data: 860278-87-1(Hazardous Substances Data)

Upstream product

• 363-52-0 3-fluorocatechol 

Downstream Products

• 860279-17-0 (E)-2-(4-chloro-2-fluoro-6-hydroxyphenyl)-2-phenylethenylphosphonic acid 
• 860279-12-5 7-chloro-5-fluoro-2-hydroxy-4-phenyl-2H-1,2λ⁵-benzoxaphosphinine 2-oxide 
• 860278-97-3 2,7-dichloro-5-fluoro-4-phenyl-2H-1,2λ⁵-benzoxaphosphinine 2-oxide 

Relevant articles and documents

Reactions of phenylenedioxytrihalophosphoranes with arylacetylenes: VII. Reaction of 2,2,2-trichloro-4-fluoro-1,3,2λ5- benzodioxaphosphole with phenylacetylene

2,2,2-Trichloro-4-fluoro-1,3,2λ5-benzodioxaphosphole reacts with phenylacetylene to give 2,7-dichloro-5-fluoro-4-phenyl-2H-1, 2λ5-benzoxaphosphinine 2-oxide. Hydrolysis of the latter leads to opening of the oxaphosphinine ring with formation of (E)-2-(4-chloro-2- fluoro-6-hydroxyphenyl)-2-phenylethenylphosphonic acid.