863727-65-5

Basic information

• Product Name: 1-(diphenylmethylene)-2-(2-methoxy-5-methylphenyl)hydrazine
• Synonyms: 1-(diphenylmethylene)-2-(2-methoxy-5-methylphenyl)hydrazine
• CAS NO: 863727-65-5
• Molecular Weight: 316.403
• Mol File: 863727-65-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(diphenylmethylene)-2-(2-methoxy-5-methylphenyl)hydrazine(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(diphenylmethylene)-2-(2-methoxy-5-methylphenyl)hydrazine(863727-65-5)
• EPA Substance Registry System: 1-(diphenylmethylene)-2-(2-methoxy-5-methylphenyl)hydrazine(863727-65-5)

Safety Data

• Hazardous Substances Data: 863727-65-5(Hazardous Substances Data)

Upstream product

• 104-93-8 p-methylanizole 
• 908093-98-1 diazodiphenylmethane 
• 5350-57-2 benzophenone hydrazone 
• 50597-88-1 2-iodo-4-methylanisole 

Downstream Products

• 863727-66-6 3-tert-butyl-1-(2-methoxy-5-methylphenyl)-1H-pyrazol-5-amine 

Relevant articles and documents

tBuLi-Promoted Intermolecular Regioselective Nucleophilic Addition of Arenes to Diazo Compounds as N-Terminal Electrophiles: Efficient Synthesis of Hydrazine Derivatives

The tBuLi-promoted intermolecular direct nucleophilic addition of arenes to diazo compounds as the N-terminal electrophiles has been developed. This reaction proceeds in a completely regioselective manner and is an efficient method for the preparation of hydrazine derivatives in high to excellent yields. This transformation not only provides an efficient approach for aromatic C–N bond formation under transition-metal-free and oxidant-free conditions but also represents a strategy for the 3-amination of pyridines and the dearomatization of indoles.