865565-60-2

Basic information

• Product Name: (1R,2S)-1-(p-methoxyphenyl)but-3-ene-1,2-diol
• Synonyms: (1R,2S)-1-(p-methoxyphenyl)but-3-ene-1,2-diol
• CAS NO: 865565-60-2
• Molecular Weight: 194.23
• Mol File: 865565-60-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (1R,2S)-1-(p-methoxyphenyl)but-3-ene-1,2-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S)-1-(p-methoxyphenyl)but-3-ene-1,2-diol(865565-60-2)
• EPA Substance Registry System: (1R,2S)-1-(p-methoxyphenyl)but-3-ene-1,2-diol(865565-60-2)

Safety Data

• Hazardous Substances Data: 865565-60-2(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 135340-32-8 (-)-B-<3-(diisopropylaminodimethylsillyl)allyl>diisopinocampheylborane 
• 106948-24-7 (allyl)(diisopropylamino)dimethylsilane 
• 51410-44-7 1-(4-methoxylphenyl)-2-propen-1-ol 
• 2181-42-2 trimethylsulphonium iodide 

Downstream Products

• 933471-53-5 (2R,3S)-3-benzyloxycarbonyl-2-p-methoxyphenylpiperidine 
• 914618-56-7 (1R,2S)-benzyl N-allyl-N-(2-benzyloxy-1-p-methoxyphenylbut-3-enyl)carbamate 
• 914618-52-3 (2R,3S)-1-benzyloxycarbonyl-(3-benzyloxy-2-p-methoxyphenyl)piperidine 
• 914618-57-8 (2R,3S)-1-benzyloxycarbonyl-(3-benzyloxy-2-p-methoxyphenyl)-1,2,3,6-tetrahydropyridine 
• 952143-97-4 benzyl (1R,2S)-2-(benzyloxy)-1-(4-methoxyphenyl)-5-oxoheptadecyl carbamate 
• 952143-96-3 benzyl (1R,2S)-2-(benzyloxy)-1-(4-methoxyphenyl)-5-oxoheptadecen-(3E)-enyl carbamate 
• 914618-53-4 (1R,2S)-benzyl N-(2-benzyloxy-1-p-methoxyphenylbut-3-enyl)carbamate 
• 914618-54-5 (1R,2S)-1,2-bis(benzyloxy)-1-p-methoxyphenylbut-3-ene 
• 865565-43-1 (1R,2S)-1,2-dimethoxy-1-(p-methoxyphenyl)but-3-ene 

Relevant articles and documents

Highly regioselective homoallyl alcohol protection through ring opening of p-methoxybenzylidene acetal

A highly regioselective homoallylic alcohol protection was achieved in the reductive cleavage of anisylidene acetal with DIBAL-H during the selective protection of hydroxyl group in terminal unsaturated diols which was unlikely compare to the diols present adjacent to internal and cyclic double bond. Reductive cleavage of terminal olefenic diols protected as its acetals gave exclusively allyl alcohol product in good to excellent yield. Though the actual reason of such observation is not quite clear, the current reductive protocol can be applied as an efficient solution for indirect protection of less reactive hydroxy group in preference to that of more reactive allylic one as PMB-mono ether.

An efficient stereoselective synthesis of (+)-deoxoprosophylline

An efficient stereoselective synthesis of (+)-deoxoprosophylline from readily available p-anisaldehyde is described. Key steps in the synthesis include the stereoselective amination of anti-1,2-dibenzyl ether using chlorosulfonyl isocyanate, intermolecula

A concise synthesis of (-)-cytoxazone and (-)-4-epi-cytoxazone using chlorosulfonyl isocyanate

A concise synthesis of (-)-cytoxazone and its stereoisomer (-)-4-epi-cytoxazone, novel cytokine modulators, has been accomplished each in six steps from readily available p-anisaldehyde with good diastereoselectivity. Key steps in the synthesis include th