86605-93-8

Basic information

• Product Name: 4-bromo-α-(trimethylsilyl)toluene
• Synonyms: 4-bromo-α-(trimethylsilyl)toluene
• CAS NO: 86605-93-8
• Molecular Formula: C₁₀H₁₅BrOSi
• Molecular Weight: 259.215
• Mol File: 86605-93-8.mol
• Article Data: 43

Chemical Properties

• Melting Point: 26-29 °C(lit.)
• Flash Point: 110 °C
• Appearance: /
• Density: 1.190 g/mL at 20 °C(lit.)
• Refractive Index: n20/D 1.531
• CAS DataBase Reference: 4-bromo-α-(trimethylsilyl)toluene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-bromo-α-(trimethylsilyl)toluene(86605-93-8)
• EPA Substance Registry System: 4-bromo-α-(trimethylsilyl)toluene(86605-93-8)

Safety Data

• Hazardous Substances Data: 86605-93-8(Hazardous Substances Data)

Upstream product

• 33861-17-5 phenyl trimethylsilyl selenide 
• 1122-91-4 4-bromo-benzaldehyde 
• 873-75-6 4-bromobenzenemethanol 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 75-77-4 chloro-trimethyl-silane 
• 216443-67-3 4-bromo-1-[(ethoxymethoxy)methyl]benzene 
• 130534-91-7 1-bromo-4-[(methoxymethyloxy)methyl]benzene 
• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 

Downstream Products

• 873-75-6 4-bromobenzenemethanol 
• 21388-92-1 4-bromobenzyl acetate 
• 55883-45-9 4-bromobenzyliodide 
• 1122-91-4 4-bromo-benzaldehyde 
• 146800-13-7 Tris(4-hydroxymethylphenyl)bismuthine 
• 51176-48-8 4-Propargylbenzyl alcohol 
• 2740-89-8 1-bromo-4-(thiocyanatomethyl)benzene 
• 25062-46-8 4-bromobenzaldehyde oxime 
• 67627-98-9 p-bromo-α,α-dichlorotoluene 

Relevant articles and documents

SYNTHESIS STRATEGY FOR GAP PROTECTING GROUP

The present invention relates to a novel synthesis method to form particular molecules. These molecules have multiple uses, most notably in the field of protecting groups used throughout organic and synthetic chemistry. The disclosed method is safer, more

Graphene oxide-bound electron-deficient tin(IV) porphyrin: a highly efficient and selective catalyst for trimethylsilylation of alcohols and phenols with hexamethyldisilazane

The catalytic activity of graphene oxide-bound tetrakis(p-aminophenyl)porphyrinatotin(IV) trifluoromethanesulfonate, [SnIV(TNH2PP)(OTf)2], in the trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) is reported. The prepared catalyst was characterized using inductively coupled plasma analysis, scanning electron microscopy, transmission electron microscopy, and Fourier transform infrared and diffuse reflectance UV–visible spectroscopies. This heterogeneous catalyst was used for selective trimethylsilylation of various alcohols and phenols with HMDS in short reaction times and high yields. Also, the catalyst is of high reusability and stability, in that it was recovered several times without loss of its initial activity. The chemoselectivity of this catalytic system in the silylation of primary alcohols in the presence of secondary and tertiary alcohols and also phenols was investigated.

Room temperature silylation of alcohols catalyzed by metal organic frameworks

The commercial Al(OH)(BDC) (BDC: 1,4-benzenedicarboxylic acid) metal organic framework (Basolite A100) is a suitable heterogeneous catalyst for the silylation of benzylic and aliphatic alcohols by hexamethyldisilazane in toluene at room temperature. Al(OH