866457-05-8

Basic information

• Product Name: (1R,2S)-2-(1,1-dimethylethoxy)-1,2-diphenylethanol
• Synonyms: (1R,2S)-2-(1,1-dimethylethoxy)-1,2-diphenylethanol
• CAS NO: 866457-05-8
• Molecular Weight: 270.371
• Mol File: 866457-05-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2S)-2-(1,1-dimethylethoxy)-1,2-diphenylethanol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S)-2-(1,1-dimethylethoxy)-1,2-diphenylethanol(866457-05-8)
• EPA Substance Registry System: (1R,2S)-2-(1,1-dimethylethoxy)-1,2-diphenylethanol(866457-05-8)

Safety Data

• Hazardous Substances Data: 866457-05-8(Hazardous Substances Data)

Upstream product

• 866457-01-4 [2S-(2α(1S*,2R*),3aα,4β,7β,7aα)]-[2-(1,1-dimethylethoxy)-1,2-diphenylethoxy]octahydro-7,8,8-trimethyl-4,7-methanobenzofuran 
• 866456-99-7 [2S-(2α(1S*,2R*),3aα,4β,7β,7aα)]-2-[2-(2-iodo-1,1-dimethylethoxy)-1,2-diphenyl-ethoxy]octahydro-7,8,8-trimethyl-4,7-methanobenzofuran 
• 866456-94-2 [2S-(2α(1R*,2S*),3aα,4β,7β,7aα)]-2-[2-[(octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy]-1,2-diphenylethoxy]-2-methylpropane-1-ol 
• 866456-98-6 methanesulfonic acid [2S-(2α(1R*,2S*),3aα,4β,7β,7aα)]-2-[2-[(octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy]-1,2-diphenylethoxy]-2-methylpropyl ester 
• 866456-92-0 [2S-(2α(1R*,2S*),3aα,4β,7β,7aα)]-2-[2-[(octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy]-1,2-diphenylethoxy]-2-methylpropionic acid 1,1-dimethylethyl ester 
• 866456-97-5 4-methylbenzene-1-sulfonic acid [2S-(2α(1R*,2S*),3aα,4β,7β,7aα)]-2-[2-[(octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy]-1,2-diphenylethoxy]-2-methylpropyl ester 

Downstream Products

• 866457-10-5 oxophenylacetic acid (1R,2S)-2-(1,1-dimethylethoxy)-1,2-diphenylethyl ester 

Relevant articles and documents

Synthesis of novel chiral hydrobenzoin mono-tert-butyl ethers derived from m-hydrobenzoin and their application as chiral auxiliaries in the diastereoselective reduction of α-keto esters

Three m-hydrobenzoin derived chiral hydrobenzoin mono-tert-butyl ethers were synthesized by a new reaction pathway and tested as chiral auxiliaries in the L-selectride mediated stereoselective reduction of their corresponding phenyl glyoxylates. As a result, improved stereoselectivities of up to a ratio of 92:8 compared to 84:16 with the initially examined analogous benzyl ether were achieved.