868564-67-4Relevant articles and documents
Highly diastereoselective Diels-Alder reactions with enantiopure sulfinyl-substituted 1-hydroxymethyldienes
De La Pradilla, Roberta Fernandez,Montero, Carlos,Tortosa, Mariola,Viso, Aima
, p. 5136 - 5145 (2007/10/03)
Enantiopure hydroxy-2- and -3-sulfinyldienes undergo highly selective Diels-Alder cycloadditions with various dienophiles controlled by the chiral sulfur atom. The related hydroxy-2-sulfonyldienes display complementary π-facial selectivity.