87100-15-0Relevant articles and documents
Manganese(III)-Promoted Double Carbonylation of Anilines Toward α-Ketoamides Synthesis
Chen, Bo,Kuai, Chang-Sheng,Xu, Jian-Xing,Wu, Xiao-Feng
supporting information, p. 487 - 492 (2021/12/06)
Employing anilines as nucleophiles in double carbonylation is a longstanding challenge. In this communication, a Mn(III)-promoted double carbonylation of alkylborates or Hantzsch esters with anilines toward the synthesis of α-ketoamides has been developed. By using easily available potassium alkyltrifluoroborates or Hantzsch esters as the starting material, and cheap and non-toxic Mn(OAc)3 ? 2H2O as the promotor, a broad range of alkyl α-ketoamide derivatives were synthesized in moderate to good yields with excellent selectivity. (Figure presented.).
Preparation method of alkyl boride
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Paragraph 0033-0037, (2021/03/30)
The invention discloses a preparation method of alkyl boride. According to the method, alkyl halides (I, Br) and 2, 2 '-biphenyl [D] [1, 3, 2] dioxaborole (B2cat2) are used as raw materials, a properamount of electrolyte (optionally) is added, and the cor
(o-Phenylenediamino)borylstannanes: Efficient Reagents for Borylation of Various Alkyl Radical Precursors
Suzuki, Kensuke,Nishimoto, Yoshihiro,Yasuda, Makoto
supporting information, p. 3968 - 3973 (2020/12/30)
(o-Phenylenediamino)borylstannanes were newly synthesized to achieve radical boryl substitutions of a variety of alkyl radical precursors. Dehalogenative, deaminative, decharcogenative, and decarboxylative borylations proceeded in the presence of a radica
