87326-32-7

Basic information

• Product Name: ALLYL-2,3-DI-O-BENZYL-ALPHA-D-GLUCOPYRANOSIDE
• Synonyms: ALLYL-2,3-DI-O-BENZYL-ALPHA-D-GLUCOPYRANOSIDE;Allyl2,3-di-O-benzyl-a-D-glucopyranoside
• CAS NO: 87326-32-7
• Molecular Formula: C₂₃H₂₈O₆
• Molecular Weight: 400.46482
• Mol File: 87326-32-7.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ALLYL-2,3-DI-O-BENZYL-ALPHA-D-GLUCOPYRANOSIDE(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYL-2,3-DI-O-BENZYL-ALPHA-D-GLUCOPYRANOSIDE(87326-32-7)
• EPA Substance Registry System: ALLYL-2,3-DI-O-BENZYL-ALPHA-D-GLUCOPYRANOSIDE(87326-32-7)

Safety Data

• Hazardous Substances Data: 87326-32-7(Hazardous Substances Data)

Usage

General Description

ALLYL-2,3-DI-O-BENZYL-ALPHA-D-GLUCOPYRANOSIDE is a chemical compound that belongs to the class of glycosides, which are molecules consisting of a sugar moiety linked to a non-sugar moiety. This specific compound is characterized by the presence of an allyl group and two benzyl groups attached to a glucose molecule. It is commonly used in organic synthesis as a protecting group for the hydroxyl group of the glucose molecule, allowing for selective chemical reactions to occur on other parts of the molecule. It has also been found to have potential pharmacological activities, particularly in the field of anti-inflammatory and anti-cancer research. Overall, ALLYL-2,3-DI-O-BENZYL-ALPHA-D-GLUCOPYRANOSIDE has important applications in both chemical synthesis and medicinal chemistry.

Upstream product

• 103833-57-4 allyl 4,6-O-benzylidene-2,3-di-O-benzyl-α-D-glucopyranoside 
• 87326-31-6 1-O-allyl-2,3-di-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 93382-48-0 allyl 4,6-O-benzylidene-α-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 2280-44-6 D-Glucose 

Downstream Products

• 143836-20-8 (2S,4aR,6S,7R,8S,8aR)-6-Allyloxy-7,8-bis-benzyloxy-2-methyl-hexahydro-pyrano[3,2-d][1,3]dioxine-2-carboxylic acid methyl ester 
• 126684-05-7 allyl 2,3-di-O-benzyl-4-O-levulinoyl-6-O-trityl-α-D-glucopyranoside 
• 87326-33-8 (2R,3R,4S,5R,6S)-6-Allyloxy-4,5-bis-benzyloxy-2-trityloxymethyl-tetrahydro-pyran-3-ol 
• 118282-21-6 methyl 2,3-di-O-benzyl-4-O-levulinoyl-α-D-glucopyranuronate 
• 126733-28-6 (2S,3S,4S,5R,6S)-6-Allyloxy-4,5-bis-benzyloxy-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-carboxylic acid 
• 128564-05-6 methyl (allyl 2,3-di-O-benzyl-4-O-levulinoyl-α-D-glucopyranosid)uronate 
• 118282-20-5 methyl (prop-1-enyl 2,3-di-O-benzyl-4-O-levulinoyl-α-D-glucopyranosid)uronate 
• 87326-44-1 methyl (prop-1-enyl 2,3-di-O-benzyl-α-D-glucopyranosid)uronate 
• 103781-67-5 methyl (prop-1-enyl 2,3-di-O-benzyl-β-L-threo-hex-4-enopyranosid)uronate 
• 87326-35-0 Acetic acid (2R,3R,4S,5R,6S)-6-allyloxy-4,5-bis-benzyloxy-2-hydroxymethyl-tetrahydro-pyran-3-yl ester 
• 87326-39-4 methyl (allyl 4-O-acetyl-2,3-di-O-benzyl-α-D-glucopyranosid)uronate 
• 87326-36-1 allyl 4-O-acetyl-2,3-di-O-benzyl-α-D-glucopyranosiduronic acid 
• 87326-40-7 methyl (prop-1-enyl 4-O-acetyl-2,3-di-O-benzyl-α-D-glucopyranosid)uronate 
• 87326-34-9 allyl 4-O-acetyl-2,3-di-O-benzyl-6-O-trityl-α-D-glucopyranoside 

Relevant articles and documents

COMPOUND RETAINED IN TUMOR

A novel compound which specifically resides in a tumor, a method for allowing it to reside in a tumor, and a method for detecting, diagnosing, and treating tumor with use thereof are provided. The present invention relates to a compound represented by chemical formula (I) wherein R is an anionic group binding to hydrogen, R1 is OH, OCOH, OCO(CH2)hCH3, or an acting group, h being an integer of 0 or more, R2 is H, OH, OCOH, OCO(CH2)iCH3, or an acting group, i being an integer of 0 or more, R3 is OH, SO3H, or an acting group, R4 is OH, SO3H, or an acting group, and R5 is OH, SO3H, or an acting group, at least one of R1, R2, R3, R4, and R5 containing an acting group, or pharmaceutically acceptable salts thereof.

SYNTHESIS OF HEPARIN FRAGMENTS. A CHEMICAL SYNTHESIS OF THE PENTASACCHARIDE O-(2-DEOXY-2-SULFAMIDO-6-O-SULFO-α-D-GLUCOPYRANOSYL)-(1->4)-O-(β-D-GLUCOPYRANOSYLURONIC ACID)-(1->4)-O-(2-DEOXY-2-SULFAMIDO-3,6-DI-O-SULFO-α-D-GLUCOPYRANOSYL)-(1->4)-O-(2-O-SULFO-

Known allyl 4,6-O-benzylidene-α-D-glucopyranoside was first converted into methyl (prop-1-enyl 2,3-di-O-benzyl-4-O-chloroacetyl-α-D-glucopyranosid)-uronate.Acid hydrolysis, followed by treatment with (bromomethylene)dimethylammonium bromide, gave methyl (