87450-67-7Relevant articles and documents
Palladium-Catalyzed Polyhetero-Claisen Rearragement of 3-(Allylthio)-1,2,4-triazin-5(4H)-ones
Mizutani, Masato,Sanemitsu, Yuzuru,Tamaru, Yoshinao,Yoshida, Zen-ichi
, p. 4585 - 4589 (1983)
The S -> N allylic transposition of 3-(allylthio)-1,2,4-triazin-5(2H)-ones (2) has been performed successfully by catalysis of a palladium(II) salt, where regioselectivities of the rearrangement (N-2 vs.N-4) are highly dependent on the substitution patter