87562-50-3

Basic information

• Product Name: 4-Pentenenitrile, 2,2-dimethyl-5-phenyl-, (4E)-
• CAS NO: 87562-50-3
• Molecular Formula: C13H15N
• Molecular Weight: 185.269
• Mol File: 87562-50-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 4-Pentenenitrile, 2,2-dimethyl-5-phenyl-, (4E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Pentenenitrile, 2,2-dimethyl-5-phenyl-, (4E)-(87562-50-3)
• EPA Substance Registry System: 4-Pentenenitrile, 2,2-dimethyl-5-phenyl-, (4E)-(87562-50-3)

Safety Data

• Hazardous Substances Data: 87562-50-3(Hazardous Substances Data)

Upstream product

• 4392-24-9 Cinnamyl bromide 
• 126-98-7 methacrylonitrile 
• 1431561-40-8 (1E, 4E)-2,2-dimethyl-5-phenylpent-4-enal oxime 
• 260352-12-3 (E)-5-(4-chlorophenyl)-2,2-diphenylpent-4-enal 
• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 78-82-0 Isobutyronitrile 

Downstream Products

• 1426431-63-1 (E)-2,2-dimethyl-5-phenylpent-4-enylamine-N,N-D₂ 
• 1206670-48-5 2-benzyl-4,4-dimethyl-1-(4-methylbenzenesulfonyl)pyrrolidine 
• 260352-12-3 (E)-5-(4-chlorophenyl)-2,2-diphenylpent-4-enal 
• 1583276-76-9 (E)-4,4-dimethyl-1-phenyldeca-1,9-dien-5-ol 
• 1583276-77-0 (E)-4,4-dimethyl-1-phenyldeca-1,9-dien-5-one 
• 1583276-42-9 (1Z,4E)-1-(4-methoxyphenyl)-2,2-dimethyl-5-phenylpent-4-en-1-one oxime 
• 1583276-43-0 (1Z,4E)-2,2-dimethyl-5-phenyl-1-(4-(trifluoromethyl)phenyl)pent-4-en-1-one oxime 
• 1583276-44-1 (1Z,4E)-2,2-dimethyl-1-(naphthalen-2-yl)-5-phenylpent-4-en-1-one oxime 
• 1583276-46-3 (1Z,4E)-2,2-dimethyl-5-phenyl-1-(thiophen-2-yl)pent-4-en-1-one oxime 
• 1583276-41-8 (2E,5E)-3,3-dimethyl-6-phenylhex-5-en-2-one oxime 
• 1583276-60-1 (1E,5E)-4,4-dimethyl-1-phenyldeca-1,9-dien-5-one oxime 
• 1431561-40-8 (1E, 4E)-2,2-dimethyl-5-phenylpent-4-enal oxime 
• 1583276-18-9 2-benzyl-4, 4-dimethyl-5-phenyl-3, 4-dihydro-2H-pyrrole 1-oxide 
• 1583276-19-0 2-benzyl-5-(4-methoxyphenyl)-4,4-dimethyl-3,4-dihydro-2H-pyrrole 1-oxide 

Relevant articles and documents

Base-catalysed asymmetric hydroamination/cyclisation of aminoalkenes utilising a dimeric chiral diamidobinaphthyl dilithium salt

A dimeric proline derived diamidobinaphthyl dilithium salt represents the first example of a chiral main group metal based catalyst for asymmetric hydroamination/cyclisation reactions of aminoalkenes. The Royal Society of Chemistry 2006.

Niobium-Catalyzed Intramolecular Addition of O-H and N-H Bonds to Alkenes: A Tool for Hydrofunctionalization

A convenient, versatile, and easy to handle intramolecular hydrofunctionalization of alkenes (C-O and C-N bonds formation) is reported using a novel niobium-based catalytic system. This atom economic and eco-friendly methodology provides an additional synthetic tool for the straightforward formation of valuable building blocks enabling molecular complexity. Various pyran, furan, pyrrolidine, piperidine, lactone, and lactam derivatives as well as spirocyclic compounds are produced in high yields and selectivities.

Substrate structural effects in yttrium(III)-catalyzed hydroamination/ cyclizations of 1,2-disubstituted and 1,1,2-trisubstituted aminoalkenes terminated by 2-(phenyl) and 2-(2-heteroarenyl) groups

A series of 2-phenyl- and 2-(2-heteroarenyl)-bearing amines possessing 1,2-disubstituted and 1,1,2-trisubststuted alkenes have been evaluated in intramolecular hydroaminations catalyzed by Y[N(TMS)(1. Aminoalkenes possessing a terminal 2-(5-trimethylsilyl)thienyl group exhibited substantially enhanced reactivity compared to their 2-(phenyl)-containing counterparts. Cyclization efficiencies imparted by the 2-[(5-trimethylsilyl)furanyl] substituent were comparable or only slightly better than those obtained with the simple the 2-(phenyl) group. Georg Thieme Verlag Stuttgart · New York.