87895-63-4

Basic information

• Product Name: 2-(2-aminobenzoyl)-4,5-dimethylthiophene
• CAS NO: 87895-63-4
• Molecular Weight: 231.318
• Mol File: 87895-63-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(2-aminobenzoyl)-4,5-dimethylthiophene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-aminobenzoyl)-4,5-dimethylthiophene(87895-63-4)
• EPA Substance Registry System: 2-(2-aminobenzoyl)-4,5-dimethylthiophene(87895-63-4)

Safety Data

• Hazardous Substances Data: 87895-63-4(Hazardous Substances Data)

Upstream product

• 632-16-6 2,3-dimethylthiophene 
• 525-76-8 2-methyl-4-oxo-3,1-benzoxazine 
• 87895-78-1 3-(4,5-dimethyl-2-thienyl)anthranil 
• 118-92-3 anthranilic acid 

Downstream Products

• 87895-71-4 (2-Azido-phenyl)-(4,5-dimethyl-thiophen-2-yl)-methanone 

Relevant articles and documents

An In-depth Study of the Azidobenzophenone-Anthranil-Acridone Transformation

The title transformation, particularly the conversion of anthranils into acridones, is shown to be critically sensitive to temperature, solvent, substituent, and metal catalysts.Thus the conversion of 3-(p-tolyl)anthranil into an acridone gives a ratio of 2-and 3-methyl derivatives varying from 0.6:1 to 4.7:1 with changing temperature and solvent.In other similar thermolyses, solvents (e.g. 1,2,4-trichlorobenzene) were incorporated into the product and traces of metals and their derivatives had a dramatic effect on the rate and course of the reaction.The most effective catalysts were iron powder and aluminium acetylacetonate. 3-(2,6-Disubstituted phenyl)anthranils gave acridones in which the substituents were either lost or rearranged onto N or C, the last cases involving sequential -sigmatropic shifts. 3-Thienylanthranils gave related thienoquinolones on thermolysis; again the reaction were very sensitive to catalysis.Blocked thienylanthranils also gave rearrangement products, but the non-aromatic intermediates could be isolated.