879556-27-1

Basic information

• Product Name: [(C₁₀H₇C₁₀H₆P(C₆H₅)2)(P(C₆H₅)2)Ru(BF₂OOH)]⁽¹⁺⁾*SbF₆^(1-)=[(C₁₀H₇C₁₀H₆P(C₆H₅)2)(P(C₆H₅)2)Ru(BF₂OOH)](SbF₆)
• CAS NO: 879556-27-1
• Molecular Weight: 1042.32
• Mol File: 879556-27-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(C₁₀H₇C₁₀H₆P(C₆H₅)2)(P(C₆H₅)2)Ru(BF₂OOH)]⁽¹⁺⁾*SbF₆^(1-)=[(C₁₀H₇C₁₀H₆P(C₆H₅)2)(P(C₆H₅)2)Ru(BF₂OOH)](SbF₆)(CAS DataBase Reference)
• NIST Chemistry Reference: [(C₁₀H₇C₁₀H₆P(C₆H₅)2)(P(C₆H₅)2)Ru(BF₂OOH)]⁽¹⁺⁾*SbF₆^(1-)=[(C₁₀H₇C₁₀H₆P(C₆H₅)2)(P(C₆H₅)2)Ru(BF₂OOH)](SbF₆)(879556-27-1)
• EPA Substance Registry System: [(C₁₀H₇C₁₀H₆P(C₆H₅)2)(P(C₆H₅)2)Ru(BF₂OOH)]⁽¹⁺⁾*SbF₆^(1-)=[(C₁₀H₇C₁₀H₆P(C₆H₅)2)(P(C₆H₅)2)Ru(BF₂OOH)](SbF₆)(879556-27-1)

Safety Data

• Hazardous Substances Data: 879556-27-1(Hazardous Substances Data)

Upstream product

• 104621-48-9 Ru(OAc)2(2,2'-bis(diphenylphosphine)-1,1'-binaphthyl) 

Relevant articles and documents

Structural studies on novel Ru(II)-Binap complexes

The solid-state structures for two complexes, 7 and 8, are reported. Complex 7 was prepared by treating Ru(OAc)2(Binap) with two equivalents of HBArF in toluene solution, and represents only the second solid-state structure of a Binap complex, in which the Binap is a 6e donor to the Ru(II). The bonding is maintained in solution as shown via 13C NMR studies. The unusual cation 8, as an SbF6- salt, arises from prolonged reaction of Ru(OAc)2(Binap) with wet HBF4 (and, subsequently, added HSbF6) in 1,2-dichloroethane.