880-36-4

Basic information

• Product Name: 2-N-OCTYLTHIOPHENE
• Synonyms: 2-N-OCTYLTHIOPHENE;2-OCTYLTHIOPHENE;Thiophene, 2-octyl-;2-o-Octylthiophene;2-n-Octylthiophene,98%;2-n-Octylthiophene
• CAS NO: 880-36-4
• Molecular Formula: C₁₂H₂₀S
• Molecular Weight: 196.35
• EINECS: 212-913-3
• Mol File: 880-36-4.mol
• Article Data: 26

Chemical Properties

• Melting Point: -19.15°C (estimate)
• Boiling Point: 127-129°C 12mm
• Flash Point: 127-129°C/12mm
• Appearance: /
• Density: 0.921
• Vapor Pressure: 0.0226mmHg at 25°C
• Refractive Index: 1.4920
• Storage Temp.: 0-10°C
• BRN: 114488
• CAS DataBase Reference: 2-N-OCTYLTHIOPHENE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-N-OCTYLTHIOPHENE(880-36-4)
• EPA Substance Registry System: 2-N-OCTYLTHIOPHENE(880-36-4)

Safety Data

• Safety Statements: S24/25:Avoid contact with skin and eyes.
• Hazardous Substances Data: 880-36-4(Hazardous Substances Data)

Usage

General Description

2-N-octylthiophene is a chemical compound with the molecular formula C14H26S. It is a thiophene derivative with a linear octyl side chain attached to the 2-position of the thiophene ring. 2-N-OCTYLTHIOPHENE is often used in the production of organic electronic devices such as field-effect transistors and organic photovoltaics due to its high charge carrier mobility and good solubility in common organic solvents. Additionally, 2-N-octylthiophene has been studied for its potential application in organic light-emitting diodes and as a material for chemical sensors. Its unique electronic and solubility properties make it a promising candidate for various applications in the field of organic electronics.

InChI:InChI=1/C12H20S/c1-2-3-4-5-6-7-9-12-10-8-11-13-12/h8,10-11H,2-7,9H2,1H3

Upstream product

• 188290-36-0 thiophene 
• 111-83-1 1-bromo-octane 
• 3437-95-4 2-Iodothiophene 
• 777952-08-6 8-[2]thienyl-octan-2-one 
• 30711-41-2 1-(thiophen-2-yl)octan-1-one 
• 5713-61-1 thiophen-2-yl magnesium bromide 
• 629-27-6 1-Iodooctane 
• 111-64-8 n-octanoic acid chloride 
• 1160755-78-1 C₅H₆SZn 
• 14403-26-0 dioctylzinc 
• 1003-09-4 2-bromothiophene 
• 3386-35-4 1-octyl p-toluenesulfonate 
• 68-12-2 N,N-dimethyl-formamide 
• 109-99-9 tetrahydrofuran 

Downstream Products

• 90619-88-8 5-Octyl-2-thiophenecarboxylic acid 
• 172514-63-5 2-bromo-5-octan-1-yl-thiophene 
• 925424-90-4 4,4,5,5-tetramethyl-2-(5-octylthiophen-2-yl)-1,3,2-dioxaborolane 
• 13090-49-8 dithieno[3, 4-b:3',4'-d]thiophene 
• 86373-15-1 4-[(5-Octyl-thiophen-2-ylmethyl)-amino]-benzoic acid 
• 86373-14-0 ethyl 4-{[(5-octyl-2-thienyl)methyl]amino}benzoate 
• 15594-90-8 n-henicosanol 
• 6064-90-0 methyl heneicosanoate 
• 1258753-81-9 C₅₂H₅₄O₈S₂ 
• 13910-16-2 n-octylsulfanylbenzene 
• 93164-73-9 5-octyl-2,2’-bithiophene 

Relevant articles and documents

Rational Design of an Iron-Based Catalyst for Suzuki–Miyaura Cross-Couplings Involving Heteroaromatic Boronic Esters and Tertiary Alkyl Electrophiles

Suzuki–Miyaura cross-coupling reactions between a variety of alkyl halides and unactivated aryl boronic esters using a rationally designed iron-based catalyst supported by β-diketiminate ligands are described. High catalyst activity resulted in a broad substrate scope that included tertiary alkyl halides and heteroaromatic boronic esters. Mechanistic experiments revealed that the iron-based catalyst benefited from the propensity for β-diketiminate ligands to support low-coordinate and highly reducing iron amide intermediates, which are very efficient for effecting the transmetalation step required for the Suzuki–Miyaura cross-coupling reaction.

Cross-coupling reaction of alkyl halides with alkyl grignard reagents catalyzed by cp-iron complexes in the presence of 1,3-butadiene

Iron-catalyzed cross-coupling reaction of alkyl halides with alkyl Grignard reagents by the combined use of cyclopentadienyl ligand and 1,3-butadiene additive is described. The reaction smoothly proceeds at room temperature using unactivated alkyl bromides and fluorides via non-radical mechanism, which is in sharp contrast with hitherto known Fe-catalyzed cross-coupling reactions of alkyl halides.

Boron fluoride complexing bi-pyrrole methylidyne derivative substituted by meso-position alkyl thiophene and 3,5-position electron-donating group and preparation method of derivative

The invention discloses a boron fluoride complexing bi-pyrrole methylidyne derivative substituted by meso-position alkyl thiophene and a 3,5-position electron-donating group and a preparation method of the derivative. According to the method, 2-bromothiophene serves as a starting raw material, dipyrrylmethanes substituted by meso-position alkyl thiophene is synthesized through a series of reactions, NBS bromination is conducted, and 3,5-dibromo bi-pyrrolidine is obtained; then, TCQ oxidation and boron trifluoride ether complexing are conducted, a 3,5-boron dibromo fluorine intermediate with the meso-position containing alkyl thiophene is obtained, then the intermediate is utilized to conduct an Suzuki/Stille coupled reaction with a variety of modification groups, the boron fluoride complexing bi-pyrrole methylidyne derivative substituted by a 3,5-position donor unit is obtained, and the structural formula can be found in formula I. The boron fluoride complexing bi-pyrrole methylidyne derivative substituted by meso-position alkyl thiophene and the 3,5-position electron-donating group has good stability and has potential application value in the fields of life science, solar cells, environment, energy and the like.