88335-44-8

Basic information

• Product Name: Methyl (11R,12R,13S)-(Z)-12,13-epoxy-11-hydroxy-9-octadecenoate
• CAS NO: 88335-44-8
• Molecular Weight: 326.477
• Mol File: 88335-44-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Methyl (11R,12R,13S)-(Z)-12,13-epoxy-11-hydroxy-9-octadecenoate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl (11R,12R,13S)-(Z)-12,13-epoxy-11-hydroxy-9-octadecenoate(88335-44-8)
• EPA Substance Registry System: Methyl (11R,12R,13S)-(Z)-12,13-epoxy-11-hydroxy-9-octadecenoate(88335-44-8)

Safety Data

• Hazardous Substances Data: 88335-44-8(Hazardous Substances Data)

Upstream product

• 96192-73-3 13(S)-hydroperoxy-9(Z),11(E)-octadienoic acid methyl ester 
• 186581-53-3 diazomethane 
• 67-56-1 methanol 
• 33964-75-9 (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid 

Relevant articles and documents

Iron(III) and Copper(II) Catalysed Transformations of Fatty Acid Hydroperoxides: Efficient Generation of Peroxy Radicals with Copper(II) Trifluoromethanesulphonate

Whereas methyl (9Z,11E,13S)-13-hydroperoxyoctadeca-9,11-dienoate (3) and methyl (9Z,11E,13S,15Z)-13-hydroperoxyoctadeca-9,11,15-trienoate (4) are converted by FeCl3 dietherate into epoxy alcohols and chloroepoxides, catalytic amounts of copper(II) trifluoromethanesulphonate in the presence of octanoic acid under oxygen efficiently convert the second compound into hydroperoxy dioxolanes and dioxabicycloheptanes, and methyl (5Z,8Z,11Z,13E,15S)-15-hydroperoxyeicosa-5,8,11,13-tetraenoate (15-HPETE methyl ester, 18) into hydroperoxy bisdioxolanes via an 11-peroxy radical.