88639-49-0Relevant articles and documents
Construction of Esters through Sulfuryl Fluoride (SO 2 F 2) Mediated Dehydrative Coupling of Carboxylic Acids with Alcohols at Room Temperature
Qin, Hua-Li,S Alharbi, Njud,Wang, Shi-Meng
, p. 3901 - 3907 (2019/10/11)
A facile method for the construction of esters through dehydrative coupling of carboxylic acids with alcohols is developed. The reactions are mediated by sulfuryl fluoride (SO 2 F 2) at room temperature and proceed with high efficiency. The method has several advantages including broad substrate scope, mild conditions, excellent functional group compatibility and affords high yields, even on gram scale.
METHOD FOR PRODUCING DEUTERATED PERFLUOROALYKYL METHANOL
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Page/Page column 8, (2008/06/13)
PROBLEM TO BE SOLVED: To provide a method for safely and efficiently producing a deuterated perfluoroalykyl methanol. SOLUTION: This method for producing the deuterated perfluoroalykyl methanol expressed by general formula (I): RfCD2O-A (Rf is a perfluoroalkyl; and A is D or H) comprises reducing an perfluorcarboxylic acid anhydride expressed by general formula (II): (RfCO)2O by using deuterium in the presence of a transition metal catalyst.
Facile conversion of alcohols to the corresponding 2,2,2-trifluoroethyl esters with molecular iodine and potassium carbonate in 2,2,2-trifluoroethanol
Mori, Naoshi,Togo, Hideo
, p. 880 - 882 (2007/10/03)
A simple, effective, and high-yield procedure for the oxidative conversion of primary alcohols to the corresponding 2,2,2-trifluoroethyl esters, with molecular iodine and potassium carbonate in 2,2,2-trifluoroethanol, was studied.