89023-71-2

Basic information

• Product Name: Cyclohexanemethanol, 4-(1,1-dimethylethyl)-1-nitro-, acetate (ester), cis-
• CAS NO: 89023-71-2
• Molecular Formula: C13H23NO4
• Molecular Weight: 257.33
• Mol File: 89023-71-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclohexanemethanol, 4-(1,1-dimethylethyl)-1-nitro-, acetate (ester), cis-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanemethanol, 4-(1,1-dimethylethyl)-1-nitro-, acetate (ester), cis-(89023-71-2)
• EPA Substance Registry System: Cyclohexanemethanol, 4-(1,1-dimethylethyl)-1-nitro-, acetate (ester), cis-(89023-71-2)

Safety Data

• Hazardous Substances Data: 89023-71-2(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 31970-06-6 4-t-butyl-1-nitrocyclohexane 
• 108-24-7 acetic anhydride 

Downstream Products

• 10601-39-5 trans-(4-tert-butyl-cyclohexyl)-methanol 
• 13004-06-3 cis-(4-tert-butylcyclohexyl)methanol 
• 85204-31-5 4-(tert-butyl)cyclohexylmethyl acetate 
• 19461-35-9 trans-4-(tert-butyl)cyclohexylmethyl acetate 
• 19461-34-8 cis-4-(tert-butyl)cyclohexylmethyl acetate 

Relevant articles and documents

Deoxy-nitrosugars. Stereoelectronic Control in the Reductive Denitration of Tertiary Nitro Ethers. A Synthesis of 'C-Glycosides'

The separate, radical denitration with Bu3SnH of the pyranose derivatives 3, 4, 9, and 10 gave in good yields exclusively the 'C-glycosides' 5 and 11, respectively (Scheme 1).Similar reduction of the cylohexyl derivatives 15, 16, 19 and 20 gave 4:1 mixtures of 17, 18, 21 and 22, respectively, always with predominant formation of an axial C,H-bond.In the furanose series a divergent behaviour was observed for the D-mannose-derived nitro ethers 25 and 27 and the D-ribose-derived nitro ethers 30 and 31, respectively, in that the former two gave isomerically homogeneous reduction products (26 and 28, respectively; Scheme 3) and the latter a 1:1 mixture of the diastereoisomers 32 and 33 (Scheme 4).The stereochemical results were explained on the basis of the stereoelectronic effect of the ring O-atom, the preferred conformation of the intermediate, pyramidal alkoxyalkyl radicals and steric effects in the trioxabicyclooctane ring system.