89317-92-0Relevant articles and documents
Silicon-Directed Nazarov Reactions III. Stereochemical and Mechanistic Considerations
Jones, Todd K.,Denmark, Scott E.
, p. 2397 - 2411 (2007/10/02)
The influence of remote substituents on the stereochemical outcome of electrocyclization in the silicon-directed Nazarov reaction has been examined.While the degree of stereocontrol was modest (ca. 3:1) the substituent in the major isomer (4,5 or 7-substi