90047-78-2

Basic information

• Product Name: 2-((6-methylhepta-4,5-dien-1-yl)oxy)tetrahydro-2H-pyran
• CAS NO: 90047-78-2
• Molecular Weight: 210.316
• Mol File: 90047-78-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-((6-methylhepta-4,5-dien-1-yl)oxy)tetrahydro-2H-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: 2-((6-methylhepta-4,5-dien-1-yl)oxy)tetrahydro-2H-pyran(90047-78-2)
• EPA Substance Registry System: 2-((6-methylhepta-4,5-dien-1-yl)oxy)tetrahydro-2H-pyran(90047-78-2)

Safety Data

• Hazardous Substances Data: 90047-78-2(Hazardous Substances Data)

Upstream product

• 33821-94-2 3-(tetrahydro-2H-pyran-2-yloxy)propyl bromide 
• 598-25-4 Dimethylallene 
• 917-54-4 methyllithium 

Downstream Products

• 90047-79-3 6-Methyl-4,5-heptadien-1-yl p-Toluenesulfonate 

Relevant articles and documents

Cyclizations of ω-Allenyl Radicals

Allenyl halides of structure (CH3)2C=C=CH(CH2)nX with n=3-6 have been prepared and reacted with n-Bu3SnH to generate the corresponding radicals for examination of the cyclization reactions of these reactive intermediates.The observed hydrocarbon products indicate that cyclization occurs for the n=3,4, and 5 radicals but not for the n=6 species.The n=3 radical isomerizes very efficiently by intramolecular addition to the sp carbon of the allene group.The n=5 intermediate reacts relatively slowly by attack at the near sp2 carbon.Both cyclization modes are observed for the n=4 species.The details of these radical cyclizations are discussed.