904285-63-8

Basic information

• Product Name: [(1,1,1-tris(diphenylphosphinomethyl)ethane)Co(III)(η3-crotyl)(CN)][PF6]
• Synonyms: [(1,1,1-tris(diphenylphosphinomethyl)ethane)Co(III)(η3-crotyl)(CN)][PF6]
• CAS NO: 904285-63-8
• Molecular Weight: 909.757
• Mol File: 904285-63-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(1,1,1-tris(diphenylphosphinomethyl)ethane)Co(III)(η3-crotyl)(CN)][PF6](CAS DataBase Reference)
• NIST Chemistry Reference: [(1,1,1-tris(diphenylphosphinomethyl)ethane)Co(III)(η3-crotyl)(CN)][PF6](904285-63-8)
• EPA Substance Registry System: [(1,1,1-tris(diphenylphosphinomethyl)ethane)Co(III)(η3-crotyl)(CN)][PF6](904285-63-8)

Safety Data

• Hazardous Substances Data: 904285-63-8(Hazardous Substances Data)

Upstream product

• 60969-19-9 thallium(I) hexafluorophosphate 
• 37701-79-4 [1,1,1,-tris((diphenylphosphino)methyl)ethane]cobalt(I) chloride 
• 4635-87-4 3-pentenenitrile 

Downstream Products

• 110-59-8 pentanonitrile 
• 294887-64-2 Co(II)(1,1,1-tris(diphenylphosphinomethyl)ethane)(CN)2 
• 4635-87-4 3-pentenenitrile 

Relevant articles and documents

Reactivity of 2-methyl-3-butenenitrile in the presence of catalytic amounts of various cobalt complexes in ionic liquid

The behavior of 2-methyl-3-butenenitrile (2M3BN) in the presence of catalytic amount of several cobalt complexes was evaluated. Irrespective of the nature of cobalt complexes and the experimental conditions (presence of ligand [such as P(OPh)3 or pyridine], or/and of Lewis acid [ZnCl 2, AlCl3], organic solvent or ionic liquid), the product of isomerization 2-methyl-2-butenenitrile was obtained instead of the expected rearranged product 3-pentenenitrile (3PN). This result was explained by the activation of CH bond instead of CCN bond. With 3PN, the first example of a reversible cleavage of the CCN with complex derived from Co+ was evidenced.