906361-01-1Relevant articles and documents
A reinvestigated mechanism of ribosylation of adenine under silylating conditions
Framski, Grzegorz,Gdaniec, Zofia,Gdaniec, Maria,Boryski, Jerzy
, p. 10123 - 10129 (2006)
The mechanism of chemical synthesis of adenosine has been reinvestigated. Depending on the reaction conditions and the presence of N6-protecting groups, ribosylation of adenine proceeds via different kinetic products: 3-riboadenine in strongly acidic media, 7-ribosylated derivative in the silyl method, and 1-(β-d-ribofuranosyl)adenine when applying N6-acyladenine and silylating conditions.