91174-01-5

Basic information

• Product Name: Carbamic acid, chloro-, phenylmethyl ester, sodium salt
• CAS NO: 91174-01-5
• Molecular Formula: C8H8ClNO2.Na
• Molecular Weight: 207.592
• Mol File: 91174-01-5.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Carbamic acid, chloro-, phenylmethyl ester, sodium salt(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, chloro-, phenylmethyl ester, sodium salt(91174-01-5)
• EPA Substance Registry System: Carbamic acid, chloro-, phenylmethyl ester, sodium salt(91174-01-5)

Safety Data

• Hazardous Substances Data: 91174-01-5(Hazardous Substances Data)

Upstream product

• 30830-47-8 benzyl N-chlorocarbamate 
• 621-84-1 O-benzyl carbamate 

Downstream Products

• 91230-13-6 benzyl N-(1-phenylallyl)carbamate 
• 187333-97-7 (1S,2S)-N-(benzyloxycarbonyl)-2-amino-1,2-diphenylethanol 
• 158810-74-3 (-)-(2R,3S)-methyl 3-(benzyloxycarbonylamino)-2-hydroxy-3-phenylpropanoate 
• 187333-96-6 (1S,2R)-2-(benzyloxycarbonylamino)cyclohexan-1-ol 
• 187334-05-0 (1S,2R-2-hydroxy-cyclohexyl)-carbamic acid benzyl ester 
• 331731-32-9 (1S)-N-benzyloxycarbonyl-1-(5-benzyloxy-3-methoxyphenyl)-2-hydroxyethylamine 
• 1314036-48-0 C₂₅H₂₈N₂O₂ 
• 1314042-72-2 (4S,5R)-3-[{(2'S)-(1'-benzyloxycarbonyl)aziridin-2'-yl}carbonyl]-4,5-diphenyl-2-oxazolidinone 
• 1314042-71-1 (4S,5R)-3-[{(2'R)-(1'-benzyloxycarbonyl)aziridin-2'-yl}carbonyl]-4,5-diphenyl-2-oxazolidinone 
• 1314042-77-7 (4R,7S)-1-[{(2'S)-(1'-benzyloxycarbonyl)aziridin-2'-yl}carbonyl]-7-isopropyl-4-methyl-3-phenyl-4,5,6,7-tetrahydro-1H-indazole 
• 1314042-63-1 (4S)-4-benzyl-3-[{(2'R)-(1'-benzyloxycarbonyl)aziridin-2'-yl}carbonyl]-2-oxazolidinone 
• 1314042-64-2 (4S)-4-benzyl-3-[{(2'S)-(1'-benzyloxycarbonyl)aziridin-2'-yl}carbonyl]-2-oxazolidinone 
• 1314042-74-4 (3aS-cis)-3-[{(2'S)-(1'-benzyloxycarbonyl)aziridin-2'-yl}carbonyl]-3,3a,8,8a-tetrahydro-2H-indeno[1,2-d]-2-oxazolidinone 
• 1314042-73-3 (3aS-cis)-3-[{(2'R)-(1'-benzyloxycarbonyl)aziridin-2'-yl}carbonyl]-3,3a,8,8a-tetrahydro-2H-indeno[1,2-d]-2-oxazolidinone 

Relevant articles and documents

N-Chloro- N-sodio-carbamates as a Practical Amidating Reagent for Scalable and Sustainable Amidation of Aldehydes under Visible Light

Herein, we describe the scalability and sustainability investigations toward the visible light-mediated amidation of aldehydes with N-chloro-N-sodio-carbamates. The practicality credentials of N-chloro-N-sodio-carbamates for their use in multigram scale a

Total synthesis of (-)-ephedradine A: An efficient construction of optically active dihydrobenzofuran-ring via C-H insertion reaction

The stereocontrolled total synthesis of (-)-ephedradine A (1) has been accomplished. Construction of optically active dihydrobenzofuran-ring was performed by a novel asymmetric C-H insertion reaction. After an intramolecular ester-amide exchange reaction and a Sharpless asymmetric aminohydroxylation reaction, construction of the complex macrocyclic ring was performed by Ns-strategy and an intramolecular aza-Wittig reaction. Graphical Abstract.

Synthesis of D- and L-Deoxymannojirimycin via an Asymmetric Aminohydroxylation of Vinylfuran

(Equation Presented) The Sharpless catalytic asymmetric aminohydroxylation has been applied to 2-vinylfuran, producing β-hydroxyfurfurylamine 5a with enantioexcess of >86% and 21% yield from furfural. The Cbz and TBS protected amino alcohol 5a was converted into both the D- and L-isomers of deoxymannojirimycin (DMJ) and deoxygulonojirimycin in five to seven steps and 48% and 66% overall yields. The key steps include the use of an aza-Achmatowicz reaction, a diastereoselective Luche reduction, diastereoselective dihydroxylation, and a tandem Cbz deprotection/reductive amination.