91266-03-4Relevant articles and documents
Survey of synthetic approaches to natural (peyssonenynes) and unnatural acetoxyenediynes
Garcia-Dominguez, Patricia,Alvarez, Rosana,De Lera, Angel R.
, p. 4762 - 4782 (2012)
Four convergent synthetic approaches to acetoxyenediynes have been explored to gain access to peyssonenynes A and B, which are natural products isolated from the red alga Peyssonelia caulifera. After optimization of the routes with a palmitic acid based m
Enantioselective Catalytic Crotylboration Based Syntheses of the C(7)–C(18(20)) Fragments of Polyketides Isolated from Streptomyces gramineus
Morávková, Terézia,Bedná?ová, Eva,Kotora, Martin
, (2021/10/20)
A general modular enantioselective synthetic approach to the C(7)–C(18) and the C(7)–C(20) fragment belonging to E-492, actinofuranone A, and JBIR-108 was developed. The crucial synthetic step relies on highly enantioselective crotylboration of aldehydes
A bio-inspired cascade and a late-stage directed sp3 C–H lithiation enables a concise total synthesis of (?)-virosaine A
Hughes, Jonathan M.E.,Gleason, James L.
supporting information, p. 759 - 768 (2018/01/01)
The asymmetric total synthesis of (?)-virosaine A was achieved in 9% overall yield from commercially/readily available starting materials. Inspired by an intriguing biosynthetic proposal, a novel cascade reaction sequence was developed to efficiently cons
