91376-49-7

Basic information

• Product Name: 3-Buten-2-ol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2S)-
• CAS NO: 91376-49-7
• Molecular Formula: C20H26O2Si
• Molecular Weight: 326.511
• Mol File: 91376-49-7.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: 3-Buten-2-ol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Buten-2-ol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2S)-(91376-49-7)
• EPA Substance Registry System: 3-Buten-2-ol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2S)-(91376-49-7)

Safety Data

• Hazardous Substances Data: 91376-49-7(Hazardous Substances Data)

Upstream product

• 1497395-96-6 (tert-butyl)(((4R,5S)-5-(iodomethyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methoxy)diphenylsilane 
• 169871-36-7 (4R,5R)-trans-2,2-dimethyl-4-tert-butyldiphenylsiloxymethyl-5-hydroxymethyl-1,3-dioxolane 
• 1037204-48-0 (2S)-tert-butyl-[2-(4-methoxybenzyloxy)but-3-enyloxy]diphenylsilane 
• 106731-74-2 tert-butyl[(2S)-oxiran-2-ylmethoxy]diphenylsilane 
• 1037204-47-9 C₂₆H₄₀O₂Si₂ 
• 2181-42-2 trimethylsulphonium iodide 
• 497-06-3 3,4-butenediol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 62214-39-5 (2S)-but-3-ene-1,2-diol 

Downstream Products

• 191800-36-9 3,5-Dinitro-benzoic acid (R)-1-(tert-butyl-diphenyl-silanyloxymethyl)-allyl ester 
• 62214-39-5 (2S)-but-3-ene-1,2-diol 
• 874660-28-3 tert-butyl-[2-(1-ethoxy-but-3-enyloxy)-but-3-enyloxy]-diphenyl-silane 
• 874660-54-5 tert-butyl-(6-ethoxy-5,6-dihydro-2H-pyran-2-ylmethoxy)-diphenyl-silane 
• 874660-31-8 (2R,3S,4S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-6-ethoxy-tetrahydro-pyran-3,4-diol 
• 874660-55-6 4-(tert-butyl-diphenyl-silanyloxymethyl)-6-ethoxy-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one 
• 874660-56-7 (2R,3S,4S,6R)-6-Allyl-2-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-pyran-3,4-diol 
• 874660-33-0 (3aS,4R,6R,7aS)-6-Allyl-4-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one 
• 874660-57-8 ((3aS,4R,6R,7aS)-6-Allyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-ylmethoxy)-tert-butyl-diphenyl-silane 
• 874660-34-1 3-[(3aS,4R,6R,7aS)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl]-propan-1-ol 
• 874660-58-9 [(3aS,4R,6R,7aS)-6-(3-Benzyloxy-propyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-ylmethoxy]-tert-butyl-diphenyl-silane 
• 301670-84-8 (R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-((R)-3-isopropenyl-4,5-dihydro-isoxazol-5-yl)-ethanol 
• 301670-82-6 (R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-((S)-3-isopropenyl-4,5-dihydro-isoxazol-5-yl)-ethanol 
• 223763-54-0 (4R,5S)-5-(tert-butyldiphenylsilyloxymethyl)-1-oxa-3-azabicyclo<3.1.0>hexan-2-one 

Relevant articles and documents

A convergent approach for the total synthesis of the α-glucosidase inhibitor (-)-panaxjapyne-C

The stereoselective total synthesis of (-)-panaxjapyne-C was accomplished in a convergent fashion. The synthesis utilizes the readily available enantiomers l-(+)-diethyltartrate and d-(-)-diethyltartrate and involves a Cadiot-Chodkiewicz coupling reaction, and an Ohira-Bestmann reaction as the key steps.

A modular approach to aryl-C-ribonucleosides via the allylic substitution and ring-closing metathesis sequence. A stereocontrolled synthesis of all four α-/β- and D-/L-C-nucleoside stereoisomers

Iridium(I)-catalyzed allylation of the enantiopure monoprotected copper(I) alkoxide, generated from (S)-5a, with the enantiopure allylic carbonates (R)-9a,b has been developed as the key step in a new approach to C-nucleoside analogues. The anomeric cente

Synthesis of 3-vinyl-2,5-dihydrofuran ring system via enyne metathesis

An efficient route, starting from but-3-en-1,2-diol, is described to synthesize racemic diastereoisomeric (5-ethoxy-4-vinyl-2,5-dihydrofuran-2-yl) methanol derivatives. Acyclic enyne intermediates having the alkyne moiety directly connected to the asymmet