916576-31-3

Basic information

• Product Name: 2-[(E)-2-(4-methylphenyl)ethenyl]-1,3-dioxolane
• Synonyms: 2-[(E)-2-(4-methylphenyl)ethenyl]-1,3-dioxolane
• CAS NO: 916576-31-3
• Molecular Weight: 190.242
• Mol File: 916576-31-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-[(E)-2-(4-methylphenyl)ethenyl]-1,3-dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(E)-2-(4-methylphenyl)ethenyl]-1,3-dioxolane(916576-31-3)
• EPA Substance Registry System: 2-[(E)-2-(4-methylphenyl)ethenyl]-1,3-dioxolane(916576-31-3)

Safety Data

• Hazardous Substances Data: 916576-31-3(Hazardous Substances Data)

Upstream product

• 646-06-0 1,3-DIOXOLANE 
• 766-97-2 4-n-methylphenylacetylene 
• 56578-35-9 4-methyl-cinnamaldehyde 
• 107-21-1 ethylene glycol 
• 52509-14-5 (1,3-dioxolan-2-yl-methyl)triphenylphosphonium bromide 
• 104-87-0 4-methyl-benzaldehyde 

Downstream Products

• 562812-20-8 2-(2,2-difluoro-3-p-tolyl-cyclopropyl)-[1,3]dioxolane 

Relevant articles and documents

Copper-catalyzed hydroalkylation of alkynes: Addition of sp3 C-H bonds across carbon-carbon triple bonds

The regioselective copper-catalyzed addition of sp3 C-H bonds adjacent to an oxygen atom to various alkynes has been accomplished under mild reactions conditions in the presence of tertbutyl hydroperoxide to give the corresponding alkenylated p

Phase transfer Wittig reaction with 1,3-dioxolan-2-yl-methyltriphenyl phosphonium salts: An efficient method for vinylogation of aromatic aldehydes

Aldehydes were efficiently transformed into allylic dioxolanes by a Wittig-type reaction, using 1,3-dioxolan-2-yl-methyltriphenylphosphonium bromide under phase transfer conditions. The substituent kinetic effects were studied, and related to Hammett values and electrochemical potentials.