918874-30-3

Basic information

• Product Name: dimethyl [2-(2-methoxyphenyl)-2-oxoethyl]phosphonate
• Synonyms: dimethyl [2-(2-methoxyphenyl)-2-oxoethyl]phosphonate
• CAS NO: 918874-30-3
• Molecular Weight: 258.211
• Mol File: 918874-30-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: dimethyl [2-(2-methoxyphenyl)-2-oxoethyl]phosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl [2-(2-methoxyphenyl)-2-oxoethyl]phosphonate(918874-30-3)
• EPA Substance Registry System: dimethyl [2-(2-methoxyphenyl)-2-oxoethyl]phosphonate(918874-30-3)

Safety Data

• Hazardous Substances Data: 918874-30-3(Hazardous Substances Data)

Upstream product

• 31949-21-0 bromomethyl 2-methoxyphenyl ketone 
• 606-45-1 2-methoxybenzoic acid methyl ester 
• 756-79-6 dimethyl methane phosphonate 
• 579-75-9 2-Methoxybenzoic acid 

Relevant articles and documents

Convenient access to pyrrolidin-3-ylphosphonic acids and tetrahydro-2H-pyran-3-ylphosphonates with multiple contiguous stereocenters from nonracemic adducts of a Ni(II)-catalyzed Michael reaction

A new synthetic strategy toward nonracemic phosphoryl-substituted pyrrolidines and tetrahydropyranes with three and five contiguous stereocenters is presented. Readily available β-keto phosphonates react with conjugated nitroolefins in the presence of a c

A practical preparation of aryl β-ketophosphonates

The condensation of alkyl phosphonates with aryl esters to give β-ketophosphonates may be carried out at elevated temperatures mediated by LiHMDS under Barbier type conditions. The reaction is scalable, does not require specialized cryogenic equipment, and is general for all aryl and heteroaryl esters examined.