92040-02-3Relevant articles and documents
Palladium-Based Hydroamination Catalysts Employing Sterically Demanding 3-Iminophosphines: Branched Kinetic Products by Prevention of Allylamine Isomerization
Thakuri, Rajendr S.,Schmidt, Joseph A. R.
, p. 1917 - 1927 (2019/05/21)
A new allylpalladium triflate catalyst with a dimesitylphosphine moiety was synthesized, isolated, and characterized. The greatly increased steric bulk on the phosphine of this palladium catalyst inhibited product isomerization, which is often observed after hydroamination of terminal allenes with secondary amines. The considerably reduced rate of isomerization facilitated the isolation of many previously unknown branched allylamines, products that were inaccessible when using other, more active 3-iminophosphine palladium catalysts.
Ruthenium-catalyzed regio- and enantioselective allylic amination of racemic 1-arylallyl esters
Kawatsura, Motoi,Uchida, Kenta,Terasaki, Shou,Tsuji, Hiroaki,Minakawa, Maki,Itoh, Toshiyuki
supporting information, p. 1470 - 1473 (2014/04/03)
The regio- and enantioselective allylic amination of racemic monosubstituted allylic esters, such as 1-arylallyl acetates, with cyclic secondary amines has been accomplished. The RuCl3/(S,S)-ip-pybox catalyst system has effectively catalyzed th
Allylic amination by a DNA-diene-iridium(I) hybrid catalyst
Fournier, Pierre,Fiammengo, Roberto,Jaeschke, Andres
experimental part, p. 4426 - 4429 (2009/10/23)
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