92104-69-3

Basic information

• Product Name: ((1R,2R)-2-Isopropyl-3-methyl-cyclopropyl)-benzene
• CAS NO: 92104-69-3
• Molecular Weight: 174.286
• Mol File: 92104-69-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ((1R,2R)-2-Isopropyl-3-methyl-cyclopropyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: ((1R,2R)-2-Isopropyl-3-methyl-cyclopropyl)-benzene(92104-69-3)
• EPA Substance Registry System: ((1R,2R)-2-Isopropyl-3-methyl-cyclopropyl)-benzene(92104-69-3)

Safety Data

• Hazardous Substances Data: 92104-69-3(Hazardous Substances Data)

Upstream product

• 691-38-3 (Z)-4-methyl-2-pentene 
• 110-82-7 cyclohexane 
• 908094-04-2 phenyldiazomethane 
• 67-56-1 methanol 
• 87085-15-2 benzaldehyde hydrazone 

Relevant articles and documents

MODIFICATION OF SINGLET CARBENE REACTIVITIES BY SOLVENT

The solvent effect on the reactivity of singlet carbenes has been investigated.Competition reactions between pairs of alcohols for arylcarbenes in various solvents indicates that the O-H insertion selectivity is influenced only by 1,4-dioxane.Thus, phenylcarbene is some 33 times more reactive toward methanol relative to t-butyl alcohol in 90 molpercent dioxane than without solvent.Similar competition reactions between alcohol and olefin indicate that the O-H insertion-addition selectivities of arylcarbenes are considerably altered by dioxane.These results are interpreted as indicating that dioxane stabilizes singlet carbenes by complexing with its ione pairs of electrons.