92414-06-7Relevant articles and documents
Trityl salt catalyzed stereoselective glycosylation of alcohols with 1-hydroxyribofuranose
Uchiro, Hiromi,Mukaiyama, Temaki
, p. 79 - 80 (1996)
In the presence of a catalytic amount of several trityl salts, 2,3,5-tri-O-benzyl-D-ribofuranose smoothly reacted with alcohols to give various β-ribofuranosides in high yields with high stereoselectivity while reversed stereoselectivity was observed in t
α-selective ribofuranosylation of alcohols with ribofuranosyl iodides and triphenylphosphine oxide
Oka, Natsuhisa,Kajino, Rin,Takeuchi, Kaoru,Nagakawa, Haruna,Ando, Kaori
, p. 7656 - 7664 (2014/10/15)
Ribofuranosylation of a variety of alcohols with ribofuranosyl iodides in the presence of a base and triphenylphosphine oxide afforded the corresponding α-ribofuranosides with diastereoselectivities ≥ 99:1. This reaction can be carried out under mildly basic conditions and is thus compatible with acid-sensitive functional groups.
Synthesis of β-D-ribofuranosyl-(1→3)-α-L-rhamnopyranose by in situ activating glycosylation using 1-OH sugar derivative and Me3SiBr-CoBr2-Bu4NBr-molecular sieves 4A system
Hirooka,Mori,Sasaki,Koto,Shinoda,Morinaga
, p. 1679 - 1694 (2007/10/03)
Β-D-Ribofuranosyl-(1→3)-α-L-rhamnopyranosyl-(1→3)- L-rhamnopyranose, the trisaccharide repeating unit of the C. freundii O28, 1c O-specific polysaccharide, was synthesized using in situ activating glycosylation of the 1-OH sugar derivatives and a reagent mixture of trimethylsilyl bromide, cobalt(II) bromide, tetrabutylammonium bromide, and molecular sieves 4A. Regioselective tritylation was useful for synthesizing the 3-OH derivatives of methyl, allyl, and benzyl α-L-rhamnosides.
