92414-08-9

Basic information

• Product Name: cyclohexyl 2,3,5-tri-O-benzyl-α-D-ribofuranoside
• Synonyms: cyclohexyl 2,3,5-tri-O-benzyl-α-D-ribofuranoside
• CAS NO: 92414-08-9
• Molecular Weight: 502.651
• Mol File: 92414-08-9.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: cyclohexyl 2,3,5-tri-O-benzyl-α-D-ribofuranoside(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexyl 2,3,5-tri-O-benzyl-α-D-ribofuranoside(92414-08-9)
• EPA Substance Registry System: cyclohexyl 2,3,5-tri-O-benzyl-α-D-ribofuranoside(92414-08-9)

Safety Data

• Hazardous Substances Data: 92414-08-9(Hazardous Substances Data)

Upstream product

• 13871-89-1 trimethylsilyl cyclohexyl ether 
• 64363-77-5 methyl 2,3,5-tri-O-benzyl-β-D-ribofuranoside 
• 108-93-0 cyclohexanol 
• 16838-89-4 2,3,5-tri-O-benzyl-D-ribofuranose 
• 91110-24-6 Acetic acid (2S,3R,4R,5R)-3,4-bis-benzyloxy-5-benzyloxymethyl-tetrahydro-furan-2-yl ester 

Relevant articles and documents

Dehydrative glycosylation with cyclic phosphonium anhydrides

Cyclic phosphonium anhydrides generated from bis-phosphine oxides and trifluoromethanesulfonic anhydride are shown as general coupling reagents in a dehydrative glycosylation reaction of C1-hemiacetals. This reaction protocol is characterized by a broad substrate scope and high yields, including reactions of O-, C-, N-, and S-based nucleophiles with furanose, pyranose, and deoxysugar donors.

Dehydrative glycosylation of tri-O-benzylated 1-hydroxyribofuranose catalyzed by a copper(II) complex

A phosphine/Cu(II) complex catalyzes the dehydrative glycosylation of tri-O-benzylated 1-hydroxyribofuranose to give the ribofuranoside with high stereoselectivity.

A convenient method for the preparation of disaccharides by transglycosylation of methyl glycosides

Transglycosylation of methyl glycosides with various glycosyl acceptors using a Sn(OTf)2-Me3SiCl promoter system in the presence of molecular sieves 5A afforded the corresponding glycosides. Several useful disaccharides are effectively prepared in good yields with moderate to good stereoselectivities.