92527-68-9

Basic information

• Product Name: 2-Heptanone, 6-hydroxy-6-methyl-7-(phenylmethoxy)-
• CAS NO: 92527-68-9
• Molecular Formula: C15H22O3
• Molecular Weight: 250.338
• Mol File: 92527-68-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Heptanone, 6-hydroxy-6-methyl-7-(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Heptanone, 6-hydroxy-6-methyl-7-(phenylmethoxy)-(92527-68-9)
• EPA Substance Registry System: 2-Heptanone, 6-hydroxy-6-methyl-7-(phenylmethoxy)-(92527-68-9)

Safety Data

• Hazardous Substances Data: 92527-68-9(Hazardous Substances Data)

Upstream product

• 3587-60-8 Benzyloxymethyl chloride 
• 13505-34-5 2,6-heptandione 

Relevant articles and documents

Reactions of Carbonyl Compounds with Benzyl Chloromethyl Ether of Diiodomethane in the Presence of Samarium(II) Iodide or Metallic Samarium. New Routes to 1,2-Diols, Iodohydrins and Cyclopropanols

Carbonyl compounds react with benzyl chloromethyl ether in the presence of samarium(II) iodide to afford the corresponding addition products which, when subsequently hydrogenolysed, yield 1,2-diols.Simple aldehydes and ketones react with diiodomethane in the presence of samarium metal to give iodohydrins in good yields.Under similar reaction conditions, α-halogeno substituted ketones and aromatic 1,4-diketones are converted into cyclopropanols.These cyclopropanations have been shown to rpoceed through the initial generation of samarium enolates, followed by the Simmons-Smith type reaction.A novel transformation of esters to cyclopropanols via tandem one-carbon homologation is also described.