926-02-3

Basic information

• Product Name: TERT-BUTYL VINYL ETHER
• Synonyms: TERT-BUTYL VINYL ETHER;T-BUTYL VINYL ETHER;VINYL TERTIARY-BUTYL ETHER;VINYL T-BUTYL ETHER;2-(ethenyloxy)-2-methyl-propan;2-(Ethenyloxy)-2-methylpropane;2-Methyl-2-vinyloxy-propane;Ether,tert-butylvinyl
• CAS NO: 926-02-3
• Molecular Formula: C₆H₁₂O
• Molecular Weight: 100.16
• EINECS: 1806241-263-5
• Product Categories: Monomers;Polymer Science;Vinyl Ethers
• Mol File: 926-02-3.mol
• Article Data: 5

Chemical Properties

• Melting Point: -112°C
• Boiling Point: 75-76 °C(lit.)
• Flash Point: 1 °F
• Appearance: Clear colorless to light yellow/Liquid
• Density: 0.762 g/mL at 25 °C(lit.)
• Vapor Pressure: 117mmHg at 25°C
• Refractive Index: n20/D 1.398(lit.)
• Storage Temp.: Refrigerator (+4°C) + Flammables area
• Water Solubility: Miscible with alcohol, carbon disulfide, chloroform and diethyl ether. Slightly miscible with water.
• Stability: Stable. Highly flammable. Incompatible with strong oxidizing agents. May be prone to the formation of peroxides when stored in c
• CAS DataBase Reference: TERT-BUTYL VINYL ETHER(CAS DataBase Reference)
• NIST Chemistry Reference: TERT-BUTYL VINYL ETHER(926-02-3)
• EPA Substance Registry System: TERT-BUTYL VINYL ETHER(926-02-3)

Safety Data

• Hazard Codes: F,Xi
• Statements: 11-38
• Safety Statements: 16-26-36
• RIDADR: UN 3271 3/PG 2
• WGK Germany: 3
• TSCA: Yes
• HazardClass: 3.1
• PackingGroup: II
• Hazardous Substances Data: 926-02-3(Hazardous Substances Data)

Usage

Chemical Properties

liquid

Uses

tert-Butyl vinyl ether is used in the synthesis of 3-tert-Butoxycyclobutanone by reacting with ketene using zinc(II) chloride as a catalyst. It acts as an intermediate for the functional vinyl monomer.

InChI:InChI=1/C6H12O/c1-5-7-6(2,3)4/h5H,1H2,2-4H3

Upstream product

• 106165-17-7 acetaldehyde-(tert-butyl-phenyl-acetal) 
• 111-96-6 diethylene glycol dimethyl ether 
• 865-47-4 potassium tert-butylate 
• 74-86-2 acetylene 
• 75-65-0 tert-butyl alcohol 
• 4223-11-4 ethylene glycol n-butyl vinyl diether 
• 111-34-2 -butyl vinyl ether 
• 109-92-2 ethyl vinyl ether 
• 110-75-8 2-chloroetyl vinyl ether 
• 7665-72-7 t-butyl glycidyl ether 

Downstream Products

• 102540-99-8 (+/-)-trans-2-tert-butoxy-cyclopropanecarboxylic acid methyl ester 
• 18166-09-1 [3-(1-tert-butoxy-ethoxy)-propyl]-trimethyl-silane 
• 18166-13-7 triethyl-(1-tert-butoxy-ethoxy)-silane 
• 30830-28-5 3-[(1,1-dimethylethyl)oxy]cyclobutanone 
• 24524-56-9 1-tert-Butoxy-2-isopropylidene-cyclopropane 
• 39989-13-4 3-tert-Butoxy-cyclobutane-1,1,2,2-tetracarbonitrile 
• 33598-73-1 tert-butyl cyclopropyl ether 
• 37150-71-3 (2-tert-Butoxy-cyclopropylidene)-cyclohexane 
• 113303-95-0 2-bromo-1-tert-butoxy-1-ethoxyethane 
• 73694-76-5 N,N'-bis(2-bromocyclohexyl)-2,5-piperadinedione 
• 1620-98-0 3,5-di-t-butyl-4-hydroxybenzaldehyde 
• 17355-82-7 2,2-dichlorocyclopropyl tert-butyl ether 
• 68473-30-3 methyl-d₃-vinyl ether 
• 136689-61-7 (E)-(2-ethynylcyclopropyl) tert-butyl ether 

Relevant articles and documents

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Method for producing alkenyl ethers

Alkenyl ethers are prepared by reacting the corresponding alcohols or phenols with acetylenes in the liquid phase in the presence of basic alkali metal compounds and a cocatalyst comprising compounds of the formula (Ia) and/or (Ib) R1O—(CH2CH2CH2CH2O)n—H??(Ia) R1O—(CH2CH2CH2CH2O)n—H2,??(Ia) where R1, R2 are, independently of one another, C1-C6-alkyl or C2-C6-alkenyl, or R1 and R2 together form a butyl unit and n is 1, 2, 3, 4 or 5.

17O NMR Spectra of Vinyl Ethers

The 17O spectra of 58 α,β-unsaturated (vinyl) ethers were recorded in CDCl3 solution.The dependence of the chemical shift on the number and position of alkyl substituents in the vinyl moiety and on the nature and bulkiness of the alkoxy group was explored.The oxygen chemical shifts proved to be sufficiently sensitive to structural factors to make 17O NMR spectroscopy a useful tool in the investigation of the electronic and spatial syructures of vinyl ethers. - Keywords: NMR 17O NMR Vinyl ethers