92929-51-6Relevant articles and documents
Regioselective Functionalization of Alkyl Aryl Ethers
Chawla, H. Mohindra,Pathak, Manisha
, p. 1092 - 1093 (2007/10/02)
A new procedure for regioselective functionalization of sensitive alkyl aryl ethers has been proposed as an alternative to picrate and sulphonamide derivatives.The procedure is based upon their reaction with cerium(IV) ammonium nitrate (CAN) and gives good yields of nitro substituted ethers, affording one pot synthesis of hitherto unknown 1-isopropoxy-4-nitronaphthalene, 1-butoxy-4-nitronaphthalene, 2-isopropoxy-6-nitronaphthalene and 2-butoxy-6-nitronaphthalene.A plausible mechanism has been suggested.
Oxidative Derivatisation of Aromatic Ethers
Chawla, H. Mohindra,Mittal, Ram S.
, p. 539 - 542 (2007/10/02)
Reaction of cerium(IV) ammonium nitrate with some naphthyl ethers has been studied as a substitute to traditionally used hydrolytic cleavage method for their identification.One-pot, one-step synthesis of 2,2'-dinitro-1,1'-diethoxy-4,4'-bisnaphthalene; 2,2'-diethoxy-8-nitro-4,4'-bisnaphthalene; 1,8-dinitro-2-methoxynaphthalene; 2-methoxy-8-nitronaphthalene; 1-methoxy-4-nitronaphthalene; 1-ethoxy-4-nitronaphthalene; 4-nitro-1-naphthylbenzoate; 2-methoxy-6-nitronaphthalene; 1-nitro-2-naphthylbenzoate are described.