930597-81-2Relevant articles and documents
[Cp*IrCl2]2-assisted C=C bond cleavage with water: An experimental and computational study
Sridevi, Venugopal Shanmugham,Wai, Yip Fan,Weng, Kee Leong
, p. 1173 - 1177 (2008/10/09)
Reaction of the dimeric species [Cp*IrCl2]2 with a number of organic substrates carrying a terminal alkyne functionality (RCCH) in the presence of water leads to C=C bond cleavage to form Cp*IrCl-(CH2R)(CO). The reaction pathway has been studied both experimentally and computationally.