93654-98-9

Basic information

• Product Name: Benzeneacetic acid, 1-naphthalenyl ester
• Synonyms: phenyl acetic acid naphthalen-1-yl ester;1-naphthyl phenylacetate;1-phenylacetoxynaphthalene;Benzeneacetic acid,1-naphthalenyl ester
• CAS NO: 93654-98-9
• Molecular Formula: C18H14O2
• Molecular Weight: 262.308
• Mol File: 93654-98-9.mol
• Article Data: 6

Chemical Properties

• Melting Point: 48 °C
• Boiling Point: 440.9±24.0 °C(Predicted)
• Density: 1.182±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzeneacetic acid, 1-naphthalenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetic acid, 1-naphthalenyl ester(93654-98-9)
• EPA Substance Registry System: Benzeneacetic acid, 1-naphthalenyl ester(93654-98-9)

Safety Data

• Hazardous Substances Data: 93654-98-9(Hazardous Substances Data)

Upstream product

• 103-82-2 phenylacetic acid 
• 90-15-3 α-naphthol 
• 18052-76-1 trimethoxy(1-naphthyl)silane 
• 103-80-0 phenylacetyl chloride 

Downstream Products

• 3669-44-1 1-(1-hydroxynaphthalen-2-yl)-2-phenylethanone 
• 611-45-0 1-Benzyl-naphthalene 
• 28178-96-3 4-(phenylmethyl)-1-naphthalenol 
• 36441-32-4 2-benzyl-1-naphthol 
• 3669-43-0 1-(4-hydroxy-1-naphthyl)-2-phenylethan-1-one 
• 90-15-3 α-naphthol 
• 607-58-9 1-(phenylmethoxy)naphthalene 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 103-82-2 phenylacetic acid 

Relevant articles and documents

Ac2O-Mediated Dearylacetylative Dimerization of 2-Arylacetyl-1-naphthols: Synthesis of Naphtho[1,2-b]furan-3-ones

A novel and efficient route for the synthesis of 2-Aryl-2-naphthyl naphtho[1,2-b]furan-3-ones is described via NaH/Ac2O-mediated dearylacetylative dimerization of 2-Arylacetyl-1-naphthols in refluxing THF under open-flask conditions. A plausibl

Ethyl 2-(tert-butoxycarbonyloxyimino)-2-cyanoacetate (Boc-Oxyma) as coupling reagent for racemization-free esterification, thioesterification, amidation and peptide synthesis

Here we report the synthesis and utility of ethyl 2-(tert- butoxycarbonyloxyimino)-2-cyanoacetate (Boc-Oxyma) as an efficient coupling reagent for racemization-free esterification, thioesterification, amidation reactions and peptide synthesis that uses equimolar amounts of acids and alcohols, thiols, amines or amino acids, respectively. Its application to solid phase as well as solution phase peptide synthesis is also demonstrated and a mechanistic investigation is discussed. Boc-Oxyma is similar to the well known coupling agent COMU {1-[1-cyano-2-ethoxy-2-oxoethylideneaminooxy)- dimethylaminomorpholino] uronium hexafluorophosphate} in terms of its high reactivity and mechanism of action. However, it is not only much easier to prepare, but also to recover and reuse, thereby generating far less chemical waste.

A convenient one-pot completely stereoselective synthesis of trans-4-Hydroxystilbenes and its derivatives and X-ray structure of its precursor

The synthesis of E-isomer of 4-Hydroxystilbene and its derivatives 3 by reductive elimination of the carbonyl function in 2-phenyl-1-(4-hydroxyphenyl)ethan-1-one and its derivatives 2 and the X-ray structure of 2a are described.