94123-66-7

Basic information

• Product Name: S-phenyl 2-oxo-2-phenylethanethioate
• Synonyms: S-phenyl 2-oxo-2-phenylethanethioate
• CAS NO: 94123-66-7
• Molecular Weight: 242.298
• Mol File: 94123-66-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: S-phenyl 2-oxo-2-phenylethanethioate(CAS DataBase Reference)
• NIST Chemistry Reference: S-phenyl 2-oxo-2-phenylethanethioate(94123-66-7)
• EPA Substance Registry System: S-phenyl 2-oxo-2-phenylethanethioate(94123-66-7)

Safety Data

• Hazardous Substances Data: 94123-66-7(Hazardous Substances Data)

Upstream product

• 6099-23-6 1-(phenylsulfinyl)acetophenone 
• 137524-63-1 2,2-Dichloro-1-phenyl-2-phenylsulfanyl-ethanone 
• 65544-99-2 S-phenyl 2-hydroxy-2-phenyl(thioethanoate) 
• 16222-10-9 1-phenyl-2-(phenylthio)ethanone 
• 98-86-2 acetophenone 
• 882-33-7 diphenyldisulfane 
• 611-73-4 Benzoylformic acid 
• 122-78-1 phenylacetaldehyde 
• 108-98-5 thiophenol 

Downstream Products

• 65544-99-2 S-phenyl 2-hydroxy-2-phenyl(thioethanoate) 
• 139-66-2 diphenyl sulfide 
• 884-09-3 phenyl thiobenzoate 
• 55-21-0 benzamide 
• 614-22-2 1-benzoylurea 
• 5499-34-3 N-Benzoyl-N',N'-pentamethylen-harnstoff 
• 35337-84-9 N-methoxycarbonyl benzamide 
• 15206-55-0 methyl 2-oxo-2-phenylacetate 

Relevant articles and documents

Method for continuously preparing alpha-ketone thioester by using micro-channel reaction device

The invention provides a method for continuously preparing alpha-ketone thioester by using a micro-channel reaction device, the method comprises the following steps:taking phenylacetaldehyde and thiophenol as reaction raw materials, carrying out continuous reaction in the micro-channel reaction device in the presence of an initiator and a solvent, and carrying out oxidative coupling reaction to obtain alpha-ketone thioester III; the novel alpha-ketone thioester preparation method provided by the invention is efficient, safe and simple in process operation, mild in reaction condition and easy to amplify. The reaction process is shown as a reaction formula.

Metal-Free Oxidative Thioesterification of Methyl Ketones with Thiols/Disulfides for the Synthesis of α-Ketothioesters

A direct Csp3-H bond oxidative thioesterification of methyl ketones with aromatic thiols/disulfides promoted by TBAI/K2S2O8 has been developed. The reaction provides successfully a simple and efficient method for the synthesis of functionalized α-ketothioesters of aromatic thiols. This practical methodology exhibits readily available starting materials, large-scale applicability, synthetic application, and broad functional group tolerance. A possible mechanism for the transformation is proposed.

Dihalogenation of β-ketosulfides. Synthesis of α-keto methyl esters and α-keto S-phenyl thioesters

α-Keto esters and α-keto S-phenyl thioesters are synthesized from β-keto sulfides by dihalogenation with sulfuryl chloride followed by solvolysis with methanol and acetone/water respectively.