942066-38-8

Basic information

• Product Name: tert-butyl N-[(3-hydroxy-4-phenoxybutyl)sulfonyl]carbamate
• Synonyms: tert-butyl N-[(3-hydroxy-4-phenoxybutyl)sulfonyl]carbamate
• CAS NO: 942066-38-8
• Molecular Weight: 345.417
• Mol File: 942066-38-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: tert-butyl N-[(3-hydroxy-4-phenoxybutyl)sulfonyl]carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl N-[(3-hydroxy-4-phenoxybutyl)sulfonyl]carbamate(942066-38-8)
• EPA Substance Registry System: tert-butyl N-[(3-hydroxy-4-phenoxybutyl)sulfonyl]carbamate(942066-38-8)

Safety Data

• Hazardous Substances Data: 942066-38-8(Hazardous Substances Data)

Upstream product

• 122-60-1 Phenyl glycidyl ether 
• 147751-16-4 tert-butyl (methylsulfonyl)carbamate 

Downstream Products

• 942066-23-1 3-(phenoxymethyl)-4,5-dihydro-isothiazole 1,1-dioxide 

Relevant articles and documents

Synthesis of chiral γ-sultams through intramolecular reductive amination with sulfonylcarbamate as N-source

An efficient and enantioselective palladium-catalyzed intramolecular asymmetric reductive amination with sulfonylcarbamates as N-sources was reported, providing a facile and general access to the chiral γ-sultam derivatives with up to 97% of enantioselect

Highly enantioselective Pd-catalyzed asymmetric hydrogenation of activated imines

(Chemical Equation Presented) Pd/bisphosphines complexes are highly effective catalysts for asymmetric hydrogenation of activated imines in trifluoroethanol. The asymmetric hydrogenation of N-diphenylphosphinyl ketimines 3 with Pd(CF3CO2)/(S)-SegPhos indicated 87-99% ee, and N-tosylimines 5 could gave 88-97% ee with Pd-(CF3CO 2)/(S)-SynPhos as a catalyst. Cyclic N-sulfonylimines 7 and 11 were hydrogenated to afford the useful chiral sultam derivatives in 79-93% ee, which are important organic synthetic intermediates and structural units of agricultural and pharmaceutical agents.