942516-66-7

Basic information

• Product Name: (2,4-bis-tert-butyl-1-methoxy-3-neopentylcyclopentadienyl)(tricyclohexylphosphine)chlororuthenium(III)
• Synonyms: (2,4-bis-tert-butyl-1-methoxy-3-neopentylcyclopentadienyl)(tricyclohexylphosphine)chlororuthenium(III)
• CAS NO: 942516-66-7
• Molecular Weight: 694.427
• Mol File: 942516-66-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2,4-bis-tert-butyl-1-methoxy-3-neopentylcyclopentadienyl)(tricyclohexylphosphine)chlororuthenium(III)(CAS DataBase Reference)
• NIST Chemistry Reference: (2,4-bis-tert-butyl-1-methoxy-3-neopentylcyclopentadienyl)(tricyclohexylphosphine)chlororuthenium(III)(942516-66-7)
• EPA Substance Registry System: (2,4-bis-tert-butyl-1-methoxy-3-neopentylcyclopentadienyl)(tricyclohexylphosphine)chlororuthenium(III)(942516-66-7)

Safety Data

• Hazardous Substances Data: 942516-66-7(Hazardous Substances Data)

Upstream product

• 942516-63-4 di[(2,4-bis-tert-butyl-1-methoxy-3-neopentylcyclopentadienyl)dichlororuthenium(III)] 
• 2622-14-2 tricyclohexylphosphine 
• 942516-63-4 [RuCl2(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)]2 

Relevant articles and documents

A new coupling reaction for the synthesis of ruthenium half-sandwich complexes with sterically demanding cyclopentadienyl ligands

The reaction of RuCl3(solv.)n with tert-butylacetylene in methanol or ethanol leads to the formation of chloro-bridged half-sandwich complexes with sterically demanding cyclopentadienyl ligands, which are of high interest as starting materials for the synthesis of novel Ru catalysts. The Royal Society of Chemistry.