94397-78-1Relevant articles and documents
Asymmetric Hydrosilylation of β-Silyl Styrenes Catalyzed by a Chiral Palladium Complex
He, Yu-Han,Ji, Yang,Li, Rui,Su, Yan,Wang, Yi-Fan
, (2022/02/10)
A palladium complex coordinated with a chiral SIPHOS ligand was evaluated as an efficient catalyst for asymmetric hydrosilylation of β-silyl styrenes with trichlorosilane and 23 1,2-bis(silyl) chiral compounds were produced. Good to excellent enantioselec
Structural Characterization and Unique Catalytic Performance of Silyl-Group-Substituted Geminal Dichromiomethane Complexes Stabilized with a Diamine Ligand
Murai, Masahito,Taniguchi, Ryuji,Hosokawa, Naoki,Nishida, Yusuke,Mimachi, Hiroko,Oshiki, Toshiyuki,Takai, Kazuhiko
supporting information, p. 13184 - 13192 (2017/09/26)
Stabilization by a silyl group on the methylene carbon and a diamine ligand led to the isolation of gem-dichromiomethane species. X-ray crystallography confirmed the identity of the structure of this rare example of reactive gem-dimetalloalkane species. T
One-pot synthesis of (E)-styryl ketones from styrenes
Pawluc, Piotr,Szudkowska, Justyna,Hreczycho, Grzegorz,Marciniec, Bogdan
supporting information; experimental part, p. 6438 - 6441 (2011/09/15)
A new, efficient protocol for the highly stereoselective one-pot synthesis of (E)-styryl ketones from styrenes based on sequential ruthenium-catalyzed silylative coupling-rhodium-catalyzed desilylative acylation reactions is reported.