94453-46-0Relevant articles and documents
Development of a highly α-regioselective indium-mediated allylation reaction in water
Loh, Teck-Peng,Tan, Kui-Thong,Yang, Jian-Ying,Xiang, Chao-Li
, p. 8701 - 8703 (2001)
Linear α homoallylic alcohol adducts were obtained with high regioselectivities in moderate to good yields using allylic indium reagents in the presence of 10 M water. The exceptionally high regioselectivities observed were neither steric nor electronic i
Highly stereoselective synthesis of z-homoallylic alcohols by kinetic resolution of racemic secondary allyl boronates
Incerti-Pradillos, Celia A.,Kabeshov, Mikhail A.,Malkov, Andrei V.
supporting information, p. 5338 - 5341 (2013/06/05)
α to Z: Racemic α-chiral allyl boronates, which are readily synthesized from the respective primary allyl halides, undergo a highly efficient kinetic resolution in a face- and Z-selective allylation of aldehydes catalyzed by the chiral Bronsted acid (R)-TRIP (see scheme; Epin=tetraethylethylene glycol). Copyright
Epoxide as an aldehyde equivalent in allyl-transfer reaction with γ-adduct of homoallylic alcohol (allyl donor) giving α-adduct of homoallylic alcohol
Nokami, Junzo,Maruoka, Kazuho,Souda, Taichi,Tanaka, Nobuo
, p. 9016 - 9022 (2008/02/10)
Acid-catalyzed reactions of epoxides 2 with homoallylic alcohol γ-adducts, 1 [Me2C(OH)CHRCH{double bond, long}CH2], afford homoallylic alcohol α-adducts 3-5 via allyl-transfer reaction, sometimes being more effective than those using