94764-21-3

Basic information

• Product Name: Thioessigsaeure-<2,6-dimethyl-phenyl>-ester
• Synonyms: Thioessigsaeure-<2,6-dimethyl-phenyl>-ester
• CAS NO: 94764-21-3
• Molecular Weight: 180.271
• Mol File: 94764-21-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Thioessigsaeure-<2,6-dimethyl-phenyl>-ester(CAS DataBase Reference)
• NIST Chemistry Reference: Thioessigsaeure-<2,6-dimethyl-phenyl>-ester(94764-21-3)
• EPA Substance Registry System: Thioessigsaeure-<2,6-dimethyl-phenyl>-ester(94764-21-3)

Safety Data

• Hazardous Substances Data: 94764-21-3(Hazardous Substances Data)

Upstream product

• 34832-35-4 sodium thioacetate 
• 118-72-9 2,6-dimethylbenzene-1-thiol 
• 201230-82-2 carbon monoxide 

Downstream Products

• 129225-77-0 2,6-dimethylbenzenesulphinyl chloride 
• 75-36-5 acetyl chloride 
• 129225-67-8 2,6-dimethylbenzenesulfenyl chloride 

Relevant articles and documents

An improved, general procedure to S-aryl thiol esters: A new synthetic application of dry arenediazonium o-benzenedisulfonimides

The reaction between dry arenediazonium o-benzenedisulfonimides (1) and sodium thioacetate or thiobenzoate in anhydrous acetonitrile at room temperature is an efficient and safe procedure, of general validity, for the preparation of S-aryl thiol esters. The products can be easily purified and the yields are always very high. Of the 28 considered examples, the average yield of the S-aryl thioacetates (7) was 86% and that of the S-aryl thiobenzoates (8) 88%. It was possible to recover, in good amount and from all the reactions, o-benzenedisulfonimide (9), reusable for the preparation of salts 1.