947770-80-1Relevant articles and documents
Organic light-emitting diode having alleviated luminance reduction in low dynamic range
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Page/Page column 61; 63-64, (2022/02/22)
The present disclosure relates to an organic light-emitting diode which can operate at a low voltage with high efficiency and exhibits the effect of having an alleviated luminance reduction rate in a low dynamic range. More particularly, the organic light-emitting diode comprises: a first electrode; a second electrode facing the first electrode; and a light-emitting layer and a charge balance control layer arranged sequentially between the first and the second electrode, wherein the light-emitting layer includes at least one of amine derivative compounds represented by the following Chemical Formula A and the charge balance control layer includes at least one of anthracene derivative compounds represented by the following Chemical Formula B or C. The structures of Chemical Formulas A, B, and C are as defined in the specification.
Visible Light-Induced Borylation of C-O, C-N, and C-X Bonds
Arman, Hadi D.,Dang, Hang. T.,Haug, Graham C.,He, Ru,Jin, Shengfei,Larionov, Oleg V.,Nguyen, Viet D.,Nguyen, Vu T.,Schanze, Kirk S.
supporting information, (2020/02/04)
Boronic acids are centrally important functional motifs and synthetic precursors. Visible light-induced borylation may provide access to structurally diverse boronates, but a broadly efficient photocatalytic borylation method that can effect borylation of a wide range of substrates, including strong C-O bonds, remains elusive. Herein, we report a general, metal-free visible light-induced photocatalytic borylation platform that enables borylation of electron-rich derivatives of phenols and anilines, chloroarenes, as well as other haloarenes. The reaction exhibits excellent functional group tolerance, as demonstrated by the borylation of a range of structurally complex substrates. Remarkably, the reaction is catalyzed by phenothiazine, a simple organic photocatalyst with MW 200 that mediates the previously unachievable visible light-induced single electron reduction of phenol derivatives with reduction potentials as negative as approximately - 3 V versus SCE by a proton-coupled electron transfer mechanism. Mechanistic studies point to the crucial role of the photocatalyst-base interaction.
COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING SAME, AND ELECTRONIC DEVICE THEREFOR
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Paragraph 0091-0093; 0100-0102, (2020/02/19)
The present disclosure provides: a compound capable of providing high light-emitting efficiency, low driving voltage, and improved lifetime of a device; an organic electronic element using the same; and an electronic device therefor.