952090-61-8

Basic information

• Product Name: (2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)Pd(Ph)(Cl)(propylamine)
• CAS NO: 952090-61-8
• Molecular Weight: 688.626
• Mol File: 952090-61-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)Pd(Ph)(Cl)(propylamine)(CAS DataBase Reference)
• NIST Chemistry Reference: (2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)Pd(Ph)(Cl)(propylamine)(952090-61-8)
• EPA Substance Registry System: (2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)Pd(Ph)(Cl)(propylamine)(952090-61-8)

Safety Data

• Hazardous Substances Data: 952090-61-8(Hazardous Substances Data)

Upstream product

• 657408-07-6 dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane 
• 107-10-8 propylamine 
• 108-90-7 chlorobenzene 

Relevant articles and documents

Electronic effects on the selectivity of Pd-catalyzed C-N bond-forming reactions using biarylphosphine ligands: The competitive roles of amine binding and acidity

(Chemical Equation Presented) Electronic influence: Correlation between the relative binding constants of amines to isolated [SPhosPd(Ph)C;] (SPhos = 2-dicyclohexylphosphino-2′,6′-dimethoxy-1,1′-biphenyl) and the pKa of the amine complexes shows that the selectivity in the catalytic arylation of amines is influenced by the electronic properties of the amine. Selectivities observed in C-N cross-coupling reactions using neutral amines can be reversed using lithium amides.