95742-90-8

Basic information

• Product Name: 1,1'-Biphenyl, 4-methoxy-4'-(phenylmethyl)-
• CAS NO: 95742-90-8
• Molecular Formula: C20H18O
• Molecular Weight: 274.362
• Mol File: 95742-90-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,1'-Biphenyl, 4-methoxy-4'-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-Biphenyl, 4-methoxy-4'-(phenylmethyl)-(95742-90-8)
• EPA Substance Registry System: 1,1'-Biphenyl, 4-methoxy-4'-(phenylmethyl)-(95742-90-8)

Safety Data

• Hazardous Substances Data: 95742-90-8(Hazardous Substances Data)

Upstream product

• 101-53-1 p-benzylphenol 
• 93296-09-4 4-methoxyphenylzinc chloride 
• 957847-59-5 C₅₇H₅₂O₁₆S₄ 
• 1589-82-8 phenylmagnesium bromide 
• 1009828-70-9 C₁₈H₂₂O₄S 
• 1160484-32-1 4-benzylphenyl tosylate 
• 5720-07-0 4-methoxyphenylboronic acid 
• 68294-33-7 4-(4-methoxy-phenyl)-benzophenone 
• 960-16-7 tributylphenylstannane 
• 589-17-3 p-bromobenzyl chloride 

Relevant articles and documents

Pincer-Nickel-Catalyzed Cross-Coupling of Aryl Sulfamates with Arylzinc Chlorides

The nickel N,N,N-pincer complex 2 was demonstrated to effectively catalyze the cross-coupling of aryl sulfamates with arylzinc chlorides under mild conditions. The reaction is suitable for a wide range of substrates, and tolerates various functional groups. A nickel N,N,N-pincer complex effectively catalyzes the cross-coupling of aryl sulfamates with arylzinc chlorides under mild conditions. The reaction is suitable for a wide range of substrates, and tolerates various functional groups.

Parallel and combinatorial liquid-phase synthesis of alkylbiphenyls using pentaerythritol support

Unfunctionalized alkylbiphenyls were fabricated by a parallel and combinatorial synthesis using pentaerythritol as a tetrapodal soluble support for a sulfonate-based traceless multifunctional linker system. Nickel N-heterocyclic carbene-catalyzed reactions of pentaerythritol tetrakis(biphenylsulfonate)s with primary alkylmagnesium bromides generated the alkylbiphenyl derivatives by desulfitative cleavage/cross-coupling of the C-S bond without any memory of the attachment on the support. Though the reactions were completed with sufficient yields in 12 h at room temperature, even with only 1.5 equiv of nucleophiles, they still retained the benefits of facile isolation observed in polymer-supported reactions.

Rhodium/N-heterocyclic carbene-catalyzed cross-couplings of aryl arenesulfonates with arylboronic acids

The combination of rhodium(I) and N-hetercyclic carbenes (NHC) was found to be effective as a catalyst for cross-coupling reactions of aryl arenesulfonates with arylboronic acids, which gave rise to the desired biaryl compounds in good yields.