95888-33-8Relevant articles and documents
Aza-aromatic polycycles based on triphenylene and acridine or acridone: Synthesis and properties
Bentabed-Ababsa, Ghenia,Bouarfa, Salima,Erb, William,Jéhan, Philippe,Le Yondre, Nicolas,Mongin, Florence,Mongin, Olivier,Porée, Fran?ois-Hugues,Roisnel, Thierry
, p. 14414 - 14424 (2021/09/03)
Acridine- and acridone-based polycyclic aromatics were prepared by using as the key steps a copper-catalysed N-arylation of 2-aminobenzaldehyde, 2-aminophenones, or ethyl 2-aminobenzoate with 2-iodotriphenylene, and an acid-mediated cyclization. The regioselectivity of this intramolecular SEAr reaction was studied by performing Hückel theory calculations on the precursors. Due to their structural similarity with some MALDI-MS matrices, two acridine-based polycycles were evaluated for this purpose. Finally, in view of structure-property relationships, preliminary studies of the photophysical properties of the synthesized acridine- and acridone-based polycycles were performed.
Access to acridones by tandem copper(i)-catalyzed electrophilic amination/Ag(i)-mediated oxidative annulation of anthranils with arylboronic acids
Huang, Yan-Xia,Huang, Zhuo-Jun,Jiang, Chun-Yong,Liang, Jing-Yi,Liang, Qiu-Ping,Shu, Bing,Xie, Hui,Zeng, Jun-Yi,Zhang, Shang-Shi,Zhou, Binhua
, p. 8487 - 8491 (2021/10/20)
An efficient and practical approach for the synthesis of medicinally important acridones was developed from anthranils and commercially available arylboronic acids by a tandem copper(i)-catalyzed electrophilic amination/Ag(i)-mediated oxidative annulation strategy. This new and straightforward protocol displayed a broad substrate scope (25 examples) and high functional group tolerance. What's more, a possible mechanistic proposal was also presented.
Substituent Effect Induces Emission Modulation of Stilbene Photoswitches by Spatial Tuning of the N/B Electronic Constraints
Chen, Pangkuan,Ji, Guangqian,Wang, Nan,Yin, Xiaodong
supporting information, (2020/07/30)
We present a family of stilbene derivatives (1-4) ortho-functionalized with an electron donor and acceptor. Their emission was tuned by donor substitutions, dictating charge transfer dependent on the N···B spatial separation. The steric reduction of subst