96040-85-6

Basic information

• Product Name: C₁₆H₂₄F₃NO₃S
• CAS NO: 96040-85-6
• Molecular Weight: 367.433
• Mol File: 96040-85-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₆H₂₄F₃NO₃S(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₂₄F₃NO₃S(96040-85-6)
• EPA Substance Registry System: C₁₆H₂₄F₃NO₃S(96040-85-6)

Safety Data

• Hazardous Substances Data: 96040-85-6(Hazardous Substances Data)

Upstream product

• 2626-63-3 1,1-dimethylheptylamine 
• 35673-10-0 bis(3-(trifluoromethyl)benzenesulfonyl) peroxide 

Relevant articles and documents

Cationic Carbon-to-Nitrogen Rearrangements in N-(Arylsulfonoxy)amines

A series of N-alkyl-O-(arylsulfonyl)hydroxylamines was prepared by the reaction of amines with bis(arylsulfonyl)peroxides.In the absence of base, these amine derivatives underwent rearrangement involving the migration of groups from carbon to nitrogen.The migratory tendencies of the groups which rearranged were found to be in the order Ph>H>alkyl>Me.The migratory aptitudes Ph/Me>72 and n-hexyl/Me=4.2 suggest that these rearrangements are polar in nature and involve electron-deficient nitrogen species.Furthermore the migration of groups was found to be sensitive to the substitution pattern at the migration origin and subject to stereoelectronic control.