96481-55-9

Basic information

• Product Name: 2-methylpent-1-en-3-ol
• Synonyms: 2-methylpent-1-en-3-ol
• CAS NO: 96481-55-9
• Molecular Weight: 100.161
• Mol File: 96481-55-9.mol
• Article Data: 25

Chemical Properties

• CAS DataBase Reference: 2-methylpent-1-en-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methylpent-1-en-3-ol(96481-55-9)
• EPA Substance Registry System: 2-methylpent-1-en-3-ol(96481-55-9)

Safety Data

• Hazardous Substances Data: 96481-55-9(Hazardous Substances Data)

Upstream product

• 78-85-3 2-methylpropenal 
• 925-90-6 ethylmagnesium bromide 
• 1838-89-7 rac-2-methylpent-1-en-3-yl acetate 
• 74-96-4 ethyl bromide 
• 763-29-1 2-Methyl-1-pentene 
• 625-27-4 2-methyl-2-pentene 
• 2564-18-3 1-phenyl-3-((dimethylamino)styryl)-5-((dimethylamino)phenyl)-2-pyrazoline 
• 4104-01-2 3-Chlor-2-methylpent-1-en 
• 96455-85-5 1,3,2-dioxaphospholane 
• 1192-22-9 2,3-epoxy-2-methylpentane 
• 5369-67-5 3-Hydroperoxy-2-methylpent-1-en 
• 7795-80-4 2-methylpentane-2,3-diol 
• 13291-18-4 isopropenylmagnesium bromide 
• 123-38-6 propionaldehyde 

Downstream Products

• 39877-56-0 Phenyl 2-Methyl-2-pentenyldithiolcarbonat 
• 84599-41-7 (R^*,S^*)-α-Ethyl-2-methyloxiranemethanol 
• 125637-07-2 (R)-3-hydroxy-2-methylpent-1-ene 
• 76919-85-2 1-(2-Methyl-oxiranyl)-propan-1-one 
• 565-69-5 ethyl isopropyl ketone 
• 139079-93-9 (R)-2-methylpent-1-en-3-yl (R)-3,3,3-trifluoro-2-methoxy-2-phenylpropanoate 
• 393530-60-4 1-[(2R,6R)-6-ethyl-5-methyl-3,6-dihydro-2H-2-pyranyl]-1-ethanone 
• 406684-20-6 5-(((S,E)-4-((2R,6R)-6-ethyl-5-methyl-3,6-dihydro-2H-pyran-2-yl)-2-methylpent-3-en-1-yl)sulfonyl)-1-phenyl-1H-tetrazole 
• 1330119-07-7 C₁₀H₁₈O₂ 
• 159170-71-5 (3R,4S,5R,6R,8R,10R,11R,12S,13R,14S)-3,4-bis<(benzyloxy)methoxy>-5,13-dihydroxy-10,11-(isopropylidenedioxy)-4,6,8,10,12,14-hexamethylhexadec-15-en-7-one 

Relevant articles and documents

Chromium-Catalyzed Production of Diols From Olefins

Processes for converting an olefin reactant into a diol compound are disclosed, and these processes include the steps of contacting the olefin reactant and a supported chromium catalyst comprising chromium in a hexavalent oxidation state to reduce at least a portion of the supported chromium catalyst to form a reduced chromium catalyst, and hydrolyzing the reduced chromium catalyst to form a reaction product comprising the diol compound. While being contacted, the olefin reactant and the supported chromium catalyst can be irradiated with a light beam at a wavelength in the UV-visible spectrum. Optionally, these processes can further comprise a step of calcining at least a portion of the reduced chromium catalyst to regenerate the supported chromium catalyst.

Mechanistic Insight into Palladium-Catalyzed Cycloisomerization: A Combined Experimental and Theoretical Study

The cycloisomerization of enynes catalyzed by Pd(OAc)2 and bis-benzylidene ethylenediamine (bbeda) is a landmark methodology in transition-metal-catalyzed cycloisomerization. However, the mechanistic pathway by which this reaction proceeds has remained unclear for several decades. Here we describe mechanistic investigations into this reaction using enynamides, which deliver azacycles with high regio- and stereocontrol. Extensive 1H NMR spectroscopic studies and isotope effects support a palladium(II) hydride-mediated pathway and reveal crucial roles of bbeda, water, and the precise nature of the Pd(OAc)2 pre-catalyst. Computational studies support these mechanistic findings and lead to a clear picture of the origins of the high stereocontrol that can be achieved in this transformation, as well as suggesting a novel mechanism by which hydrometalation proceeds.

Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes: A cationic cascade cyclization

High octane: A novel and practical syntheses of 8-oxabicyclo[3.2.1]octanes using a cationic cascade cyclization reaction has been developed (see scheme; TIPS=triisopropylsilyl). The diastereomer of the cyclization product isolated depends upon whether the acetal or aldehyde substrate is used. Copyright