97250-26-5

Basic information

• Product Name: Benzenepropanal, b-propyl-
• CAS NO: 97250-26-5
• Molecular Formula: C12H16O
• Molecular Weight: 176.258
• Mol File: 97250-26-5.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzenepropanal, b-propyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanal, b-propyl-(97250-26-5)
• EPA Substance Registry System: Benzenepropanal, b-propyl-(97250-26-5)

Safety Data

• Hazardous Substances Data: 97250-26-5(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 6728-26-3 (E)-2-Hexenal 
• 143-66-8 sodium tetraphenyl borate 
• 603-36-1 triphenylantimony 
• 108-90-7 chlorobenzene 
• 3262-89-3 triphenylboroxine 
• 98-80-6 phenylboronic acid 
• 780-69-8 triethoxyphenylsilane 
• 2996-92-1 phenyl trimethylsiloxane 
• 892224-19-0 3-phenylthiohexanoic acid (S)-ethyl ester 
• 505-57-7 2-hexenal 
• 928-96-1 (Z)-3-Hexen-1-ol 
• 102-92-1 cinnamoyl chloride 
• 108387-99-1 (E)-3-phenyl-thioprop-2-ene-oic acid (S)-ethyl ester 

Relevant articles and documents

Rhodium-Catalyzed Remote C(sp3)?H Borylation of Silyl Enol Ethers

A rhodium-catalyzed remote C(sp3)?H borylation of silyl enol ethers (SEEs, E/Z mixtures) by alkene isomerization and hydroboration is reported. The reaction exhibits mild reaction conditions and excellent functional-group tolerance. This method is compatible with an array of SEEs, including linear and branched SEEs derived from aldehydes and ketones, and provides direct access to a broad range of structurally diverse 1,n-borylethers in excellent regioselectivities and good yields. These compounds are precursors to various valuable chemicals, such as 1,n-diols and aminoalcohols.

Addition reaction of arylboronic acids to aldehydes and α,β-unsaturated carbonyl compounds catalyzed by conventional palladium complexes in the presence of chloroform

Arylboronic acids react with aldehydes and α,β-unsaturated carbonyl compounds in the presence of a base and a catalytic amount of a palladium(0) complex with chloroform, affording the corresponding addition products in good yields, and chiral benzhydrol was obtained with up to 43% e.e. using (S,S)-bppm as a ligand. General palladium complexes have no catalytic activity without chloroform. Because chloroform is essential for this reaction, these reactions would be promoted by dichloromethylpalladium(II) species.

Palladium-catalyzed enantioselective conjugate addition of arylboronic acids

(Chemical Equation Presented) The first asymmetric palladium-catalyzed conjugate addition of arylboronic acids to α,β-unsaturated aldehydes, ketones, and esters is described. For cyclic substrates, excellent chemo-, regio-, and enantioselectivities are achieved when a Pd(O2CCF 3)2/DuPHOS catalyst is applied.