97585-04-1

Basic information

• Product Name: 2-Propenoic acid, 3-(4-methylphenyl)-, ethyl ester, (2Z)-
• CAS NO: 97585-04-1
• Molecular Formula: C12H14O2
• Molecular Weight: 190.242
• Mol File: 97585-04-1.mol
• Article Data: 187

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-(4-methylphenyl)-, ethyl ester, (2Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-(4-methylphenyl)-, ethyl ester, (2Z)-(97585-04-1)
• EPA Substance Registry System: 2-Propenoic acid, 3-(4-methylphenyl)-, ethyl ester, (2Z)-(97585-04-1)

Safety Data

• Hazardous Substances Data: 97585-04-1(Hazardous Substances Data)

Upstream product

• 104-87-0 4-methyl-benzaldehyde 
• 133505-33-6 carbethoxymethyldibutyltelluronium bromide 
• 38788-38-4 dibutyl telluride 
• 105-36-2 ethyl bromoacetate 
• 1071-46-1 hydrogen ethyl malonate 
• 2678-54-8 ketene diethyl acetal 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 589-18-4 4-Methylbenzyl alcohol 
• 622-97-9 1-ethenyl-4-methylbenzene 
• 109-94-4 formic acid ethyl ester 
• 17577-28-5 (ethoxycarbonylmethyl)triphenylphosphonium chloride 
• 33604-67-0 (4-methylphenyl)azo 4-methylphenyl sulfone 
• 140-88-5 ethyl acrylate 
• 623-73-4 diazoacetic acid ethyl ester 

Downstream Products

• 100899-44-3 4-Cyano-4-naphthalen-1-yl-3-p-tolyl-butyric acid ethyl ester 
• 31207-37-1 trans-2-Ethoxycarbonyl-3-(4-methyl-phenyl)-pyrrolidon-5 
• 799768-50-6 (2R,3S)-2,3-Dihydroxy-3-p-tolyl-propionic acid ethyl ester 
• 1332887-85-0 (E)-3-(4-methylphenyl)allyl-2,2,2-trichloroacetimidate 
• 1332887-94-1 2,2,2-trichloro-N-[1-(4-methylphenyl)allyl]acetamide 
• 688362-59-6 (+/-)-1-(4-methylphenyl)-2-propenylamine 
• 126838-29-7 ethyl 3-(4-methylphenyl)-3-phenyl-2-propenoate 
• 1446139-87-2 (Z)-ethyl 3-(4-fluorophenyl)-3-(p-tolyl)acrylate 
• 1446139-86-1 (E)-ethyl 3-(4-fluorophenyl)-3-(p-tolyl)acrylate 
• 1446139-89-4 (Z)-ethyl 3-(3-fluorophenyl)-3-(p-tolyl)acrylate 

Relevant articles and documents

Photoinduced Regioselective Olefination of Arenes at Proximal and Distal Sites

The Fujiwara-Moritani reaction has had a profound contribution in the emergence of contemporary C-H activation protocols. Despite the applicability of the traditional approach in different fields, the associated reactivity and regioselectivity issues had

Palladium Nanoparticles Anchored on Magnesium Organosilicate: An Effective and Selective Catalyst for the Heck Reaction

A new and effective palladium catalyst supported on a magnesium organosilicate for application in the Heck reaction is presented. A group of compounds comprising 22 examples were synthesized in moderate to high yields (up to 99%) within a short time. The palladium supported on magnesium organosilicate catalyst was characterized as an amorphous solid by SEM, containing around 33% of palladium inside the solid, and even with this low quantity of palladium, the catalyst was very efficient in the Heck reaction. Besides, based on the Scherrer equation, the crystallite size of the synthesized palladium nanoparticles was ultrasmall (around 1.3 nm). This strategy is a simple and efficient route for the formation of C-C bonds via the Heck cross-coupling reaction.

Bimetallic Ni–Pd Synergism—Mixed Metal Catalysis of the Mizoroki-Heck Reaction and the Suzuki–Miyaura Coupling of Aryl Bromides

Abstract: A combination of Pd and Ni complexes activated aryl bromides for the thermal Mizoroki-Heck reaction and Suzuki coupling giving high yields in short reaction times. A thermal redox mechanism probably occurs whereby Ni complex transfers electron and reduces the Pd (II) to Pd (0) which then takes the reactants through the standard protocol of oxidative-addition, migratory insertion and reductive elimination, typical for the Mizoroki-Heck reaction and the Suzuki coupling. Graphic Abstract: [Figure not available: see fulltext.]