98124-49-3Relevant articles and documents
TRANSFORMATIONS OF PHENYLCYCLOPROPANES UNDER THE INFLUENCE OF VARIOUS DIACYLOXYIODO DERIVATIVES
Saginova, L. G.,Bondarenko, O. B.,Gazzaeva, R. A.,Shabarov, Yu. S.
, p. 477 - 480 (2007/10/02)
The reaction of phenylcyclopropanes with various (diacycloxyiodo)benzenes and iodine tristrifluoracetate was studied. (Bistrichloroacetoxyiodo)benzene and (bistrifluoracetoxyiodo)benzene react with phenylcyclopropanes exclusively in the small ring with the formation of the respective 1-phenyl-1,3-bis(acyloxy)propanes.Iodine tristrifluoroacetate in reaction with phenylcyclopropanes attacks both the small ring and the aromatic ring, which leads to the production of the esters of 1,3-diols and p-iodophenylcyclopropanes.Possible mechanisms are proposed for the oxidative cleavage of the trimethyl ring of phenylcyclopropanes.