99172-76-6

Basic information

• Product Name: Benzene, [(2,2-dimethoxyethyl)thio]-
• Synonyms: phenylsulfanyl-acetaldehyde dimethyl acetal;Dimethoxyphenylthioacetal;phenylmercaptoacetaldehyde dimethyl acetal;Phenylmercapto-acetaldehyd-dimethylacetal;(2,2-dimethoxy-ethylsulfanyl)-benzene;1,1-dimethoxy-2-(phenylthio)ethane
• CAS NO: 99172-76-6
• Molecular Formula: C10H14O2S
• Molecular Weight: 198.286
• Mol File: 99172-76-6.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, [(2,2-dimethoxyethyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2,2-dimethoxyethyl)thio]-(99172-76-6)
• EPA Substance Registry System: Benzene, [(2,2-dimethoxyethyl)thio]-(99172-76-6)

Safety Data

• Hazardous Substances Data: 99172-76-6(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 60-29-7 diethyl ether 
• 15890-65-0 bis-(2,2-dimethoxy-ethyl)-disulfane 
• 591-51-5 phenyllithium 
• 97-97-2 chloroacetaldehyde dimethyl acetal 
• 7252-83-7 1-bromo-2,2-dimethoxyethane 

Downstream Products

• 66303-55-7 2-(phenylthio)acetaldehyde 
• 1426261-81-5 methyl 3,5;6,7-di-O-isopropylidene-2-deoxy-2-phenylthio-β-D-glycero-D-ido-heptofuranoside 
• 1204192-94-8 2-(3-phenylsulfanyl-1H-indol-5-yl)ethanesulfonicacid methylamide 
• 95-15-8 Benzo[b]thiophene 
• 882-33-7 diphenyldisulfane 
• 23528-44-1 1,2-bis-(phenylmercapto)ethylene 
• 22447-21-8 1,1,2-tris-(phenylmercapto)ethane 
• 92552-88-0 2-phenylsulfanylmethyl-2,3-dihydro-benzo[e][1,3]oxazin-4-one 
• 66303-53-5 phenylsulfanyl-acetaldehyde-(2,4-dinitro-phenylhydrazone) 
• 259684-48-5 2-(3-amino-2-methoxypyridin-4-yl)-2-(phenylthio)acetaldehyde dimethylacetal 
• 259684-39-4 1,6-dihydro-3-(phenylthio)-7H-pyrrolo[2,3-c]pyridin-7-one 

Relevant articles and documents

An efficient synthetic protocol for the synthesis of 2-(1H-Indol-5-yl)-ethanesulfonic acid methylamide: A potential synthetic precursor for naratriptan and its novel 3-substituted derivatives

Background: The 3-Substituted indoles are found to possess a wide range of biological and pharmacological activities. The efficient and impurity free scalable preparation of 2-(1H-Indol-5-yl)-ethanesulfonic acid methylamide has been successfully achieved

Synthesis of 2-thioaldoses via BF3-promoted cycloaddition of β-methoxyvinyl sulfides with 2,3-O-isopropylidene derivatives of aldehydo-aldoses

A highly stereoselective approach to the synthesis of 2-thioaldose derivatives via BF3-promoted cycloaddition of β-methoxyvinyl sulfides with 2,3-O-isopropylidene derivatives of aldehydo-aldoses is described. Georg Thieme Verlag Stuttgart · New

Ionic liquid as catalyst and reaction medium: A simple, convenient and green procedure for the synthesis of thioethers, thioesters and dithianes using an inexpensive ionic liquid, [pmIm]Br

An easily accessible and inexpensive room temperature ionic liquid, 1-pentyl-3-methylimidazolium bromide, [pmIm]Br efficiently catalyzes the reaction of alkyl halides or acyl halides with thiols without any solvent at room temperature leading to the synthesis of thioethers and thioesters in high yields. This reaction has also been extended for the preparation of dithianes and transthioetherification. The ionic liquid is recovered and recycled for subsequent runs.